Angewandte Chemie - International Edition

, volume 60 , issue 31 , pages 16989-16993

Cobalt‐Catalyzed Chemo‐ and Enantioselective Hydrogenation of Conjugated Enynes

Yanhua Hu ¹

Zhenfeng Zhang ²

Yangang Liu ^{1, 2}

Wanbin Zhang ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs Frontier Science Center for Transformative Molecules School of Chemistry and Chemical Engineering Shanghai Jiao Tong University 800 Dongchuan Road Shanghai 200240 China |

School of Pharmacy Shanghai Jiao Tong University 800 Dongchuan Road Shanghai 200240 China |

Publication type: Journal Article

Publication date: 2021-06-24

Wiley

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR: 5.550

CiteScore: 27.6

Impact factor: 16.9

ISSN: 14337851, 15213773

DOI: 10.1002/anie.202106566

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PubMed ID: 34062038

General Chemistry

Catalysis

Abstract

The Co-catalyzed chemo- and enantioselective hydrogenation of conjugated enynes has been realized for the synthesis of chiral propargylamines with high efficiency (up to 99.9 % ee and TON=2000). Mechanism studies indicate that the accompanying Zn2+ generated from zinc reduction of the CoII complex exhibits an activating effect for the initiation of the plausible CoI/CoIII catalytic cycle.

Found

1 citation

Pospelov Evgeny

11 publications, 38 citations

h-index: 5

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

National Research University Higher School of Economics

Research interests

Asymmetric metal complex catalysis

Catalysis

Density functional theory (DFT)

Heterogeneous catalysis

Organic Chemistry

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Hu Y. et al. Cobalt‐Catalyzed Chemo‐ and Enantioselective Hydrogenation of Conjugated Enynes // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 31. pp. 16989-16993.

GOST all authors (up to 50) Copy

Hu Y., Zhang Z., Liu Y., Zhang W. Cobalt‐Catalyzed Chemo‐ and Enantioselective Hydrogenation of Conjugated Enynes // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 31. pp. 16989-16993.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/anie.202106566

UR - https://doi.org/10.1002/anie.202106566

TI - Cobalt‐Catalyzed Chemo‐ and Enantioselective Hydrogenation of Conjugated Enynes

T2 - Angewandte Chemie - International Edition

AU - Hu, Yanhua

AU - Zhang, Zhenfeng

AU - Liu, Yangang

AU - Zhang, Wanbin

PY - 2021

DA - 2021/06/24

PB - Wiley

SP - 16989-16993

IS - 31

VL - 60

PMID - 34062038

SN - 1433-7851

SN - 1521-3773

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Hu,

author = {Yanhua Hu and Zhenfeng Zhang and Yangang Liu and Wanbin Zhang},

title = {Cobalt‐Catalyzed Chemo‐ and Enantioselective Hydrogenation of Conjugated Enynes},

journal = {Angewandte Chemie - International Edition},

year = {2021},

volume = {60},

publisher = {Wiley},

month = {jun},

url = {https://doi.org/10.1002/anie.202106566},

number = {31},

pages = {16989--16993},

doi = {10.1002/anie.202106566}

}

MLA

Cite this

MLA Copy

Hu, Yanhua, et al. “Cobalt‐Catalyzed Chemo‐ and Enantioselective Hydrogenation of Conjugated Enynes.” Angewandte Chemie - International Edition, vol. 60, no. 31, Jun. 2021, pp. 16989-16993. https://doi.org/10.1002/anie.202106566.

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

scimago Q1

wos Q1

SJR

5.550

CiteScore

27.6

Impact factor

16.9

ISSN

14337851 (Print)

15213773 (Electronic)