Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β‐Acetoxy Elimination
Publication type: Journal Article
Publication date: 2021-10-13
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
34510680
General Chemistry
Catalysis
Abstract
Palladium-catalyzed remote arylative substitution was achieved for the reaction of arylboronic acids with alkenes possessing a distant acetoxy group to provide arylation products having an alkene moiety at the remote position. The use of β-acetoxy elimination as a key step in the catalytic cycle allowed for regioselective formation of unstabilized alkenes after chain walking. This reaction was applicable to various arylboronic acids as well as alkene substrates.
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Metrics
17
Total citations:
17
Citations from 2024:
8
(47.05%)
Cite this
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MLA
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GOST
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Muto K. et al. Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β‐Acetoxy Elimination // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 46. pp. 24500-24504.
GOST all authors (up to 50)
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Muto K., Kumagai T., Kakiuchi F., Kochi T. Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β‐Acetoxy Elimination // Angewandte Chemie - International Edition. 2021. Vol. 60. No. 46. pp. 24500-24504.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/anie.202111396
UR - https://doi.org/10.1002/anie.202111396
TI - Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β‐Acetoxy Elimination
T2 - Angewandte Chemie - International Edition
AU - Muto, Kazuma
AU - Kumagai, Takaaki
AU - Kakiuchi, Fumitoshi
AU - Kochi, Takuya
PY - 2021
DA - 2021/10/13
PB - Wiley
SP - 24500-24504
IS - 46
VL - 60
PMID - 34510680
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Muto,
author = {Kazuma Muto and Takaaki Kumagai and Fumitoshi Kakiuchi and Takuya Kochi},
title = {Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β‐Acetoxy Elimination},
journal = {Angewandte Chemie - International Edition},
year = {2021},
volume = {60},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/anie.202111396},
number = {46},
pages = {24500--24504},
doi = {10.1002/anie.202111396}
}
Cite this
MLA
Copy
Muto, Kazuma, et al. “Remote Arylative Substitution of Alkenes Possessing an Acetoxy Group via β‐Acetoxy Elimination.” Angewandte Chemie - International Edition, vol. 60, no. 46, Oct. 2021, pp. 24500-24504. https://doi.org/10.1002/anie.202111396.