Potassium Aluminyl Promoted Carbonylation of Ethene
Publication type: Journal Article
Publication date: 2022-02-23
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
35166007
General Chemistry
Catalysis
Abstract
The potassium aluminyl [K{Al(NONDipp )}]2 ([NONDipp ]2- =[O{SiMe2 NDipp}2 ]2- , Dipp=2,6-iPr2 C6 H3 ) activates ethene towards carbonylation with CO under mild conditions. An isolated bis-aluminacyclopropane compound reacted with CO via carbonylation of an Al-C bond, followed by an intramolecular hydrogen shift to form K2 [Al(NONDipp )(μ-CH2 CH=CO-1κ2 C1,3 -2κO)Al(NONDipp )Et]. Restricting the chemistry to a mono-aluminium system allowed isolation of [Al(NONDipp )(CH2 CH2 CO-κ2 C1,3 )]- , which undergoes thermal isomerisation to form the [Al(NONDipp )(CH2 CH=CHO-κ2 C,O)]- anion. DFT calculations highlight the stabilising influence of incorporated benzene at multiple steps in the reaction pathways.
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Metrics
32
Total citations:
32
Citations from 2024:
18
(56.25%)
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GOST
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Evans M. J. et al. Potassium Aluminyl Promoted Carbonylation of Ethene // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 16.
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Evans M. J., Neale S. E., Anker M. D., Mcmullin C. L., Coles M. P. Potassium Aluminyl Promoted Carbonylation of Ethene // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 16.
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TY - JOUR
DO - 10.1002/anie.202117396
UR - https://doi.org/10.1002/anie.202117396
TI - Potassium Aluminyl Promoted Carbonylation of Ethene
T2 - Angewandte Chemie - International Edition
AU - Evans, Matthew J
AU - Neale, Samuel E.
AU - Anker, Mathew David
AU - Mcmullin, Claire L
AU - Coles, Martyn P.
PY - 2022
DA - 2022/02/23
PB - Wiley
IS - 16
VL - 61
PMID - 35166007
SN - 1433-7851
SN - 1521-3773
ER -
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BibTex (up to 50 authors)
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@article{2022_Evans,
author = {Matthew J Evans and Samuel E. Neale and Mathew David Anker and Claire L Mcmullin and Martyn P. Coles},
title = {Potassium Aluminyl Promoted Carbonylation of Ethene},
journal = {Angewandte Chemie - International Edition},
year = {2022},
volume = {61},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/anie.202117396},
number = {16},
doi = {10.1002/anie.202117396}
}