Stereodefined Skipped Dienes through Iridium‐Catalyzed Formal Addition of Tertiary Allylic C−H Bonds to Alkynes
3
Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192 China
|
Publication type: Journal Article
Publication date: 2022-05-05
scimago Q1
wos Q1
SJR: 5.550
CiteScore: 27.6
Impact factor: 16.9
ISSN: 14337851, 15213773
PubMed ID:
35460133
General Chemistry
Catalysis
Abstract
Preparation of skipped dienes with a quaternary carbon center at the C-3 position remains a synthetic challenge. We report here an iridium-catalyzed formal addition of tertiary sp3 C-H bond to alkyne for the facile preparation of skipped dienes. The tertiary allylic C-H bond is cleaved regioselectively, at the site of which a new C-C bond is formed. Enantioselective construction of acyclic quaternary carbon stereocenters is also demonstrated.
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Metrics
15
Total citations:
15
Citations from 2024:
9
(60%)
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GOST
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Wang Z. et al. Stereodefined Skipped Dienes through Iridium‐Catalyzed Formal Addition of Tertiary Allylic C−H Bonds to Alkynes // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 26.
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Wang Z., Gao P. C., Lin E. Z., Li B. Stereodefined Skipped Dienes through Iridium‐Catalyzed Formal Addition of Tertiary Allylic C−H Bonds to Alkynes // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 26.
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RIS
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TY - JOUR
DO - 10.1002/anie.202200075
UR - https://doi.org/10.1002/anie.202200075
TI - Stereodefined Skipped Dienes through Iridium‐Catalyzed Formal Addition of Tertiary Allylic C−H Bonds to Alkynes
T2 - Angewandte Chemie - International Edition
AU - Wang, Zi-Xuan
AU - Gao, Peng Chao
AU - Lin, En Ze
AU - Li, Bijie
PY - 2022
DA - 2022/05/05
PB - Wiley
IS - 26
VL - 61
PMID - 35460133
SN - 1433-7851
SN - 1521-3773
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Wang,
author = {Zi-Xuan Wang and Peng Chao Gao and En Ze Lin and Bijie Li},
title = {Stereodefined Skipped Dienes through Iridium‐Catalyzed Formal Addition of Tertiary Allylic C−H Bonds to Alkynes},
journal = {Angewandte Chemie - International Edition},
year = {2022},
volume = {61},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/anie.202200075},
number = {26},
doi = {10.1002/anie.202200075}
}