Angewandte Chemie - International Edition

sp ² to sp ³ Hybridization Transformation in Ionic Crystals under Unprecedentedly Low Pressure

Jiang Xingxing ^{1, 2}

Molokeev Maxim S. ^{3, 4, 5}

Wang Naizheng ^{1, 6}

Wang Yonggang ⁷

Wen Ting ⁸

Zhichao Dong ⁹

Liu Youquan ^{1, 6}

Li Wei ¹⁰

Lin Zheshuai ^{1, 2, 6}

Hide authors affiliations Show authors affiliations: 10 affiliations

Functional Crystals Lab, Technical Institute of Physics and Chemistry Chinese Academy of Sciences Beijing 100190 China |

Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049 China |

Laboratory of Crystal Physics Kirensky Institute of Physics SB RAS Krasnoyarsk 660036 Russia |

⁴

Department of Physics Far Eastern State Transport University Khabarovsk 680021 Russia |

⁵

Siberian Federal University Krasnoyarsk 660041 Russia |

⁶

University of Chinese Academy of Sciences Beijing 100049 China |

⁷

School of Materials Science and Engineering Peking University Beijing 100871 China |

⁸

Center for High Pressure Science & Technology Advanced Research Beijing 100094 China |

⁹

Laboratory of Space Astronomy and Technology National Astronomical Observatories Chinese Academy of Sciences Beijing 100101 China |

¹⁰

School of Materials Science and Engineering TKL of Metal and Molecule-Based Material Chemistry Nankai University Tianjin 300350 China |

Publication type: Journal Article

Publication date: 2022-09-29

Wiley

Journal: Angewandte Chemie - International Edition

Quartile SCImago

Quartile WOS

Impact factor: 16.6

ISSN: 14337851, 15213773

DOI: 10.1002/anie.202208247

Copy DOI

General Chemistry

Catalysis

Abstract

Under cold pressure sp1 /sp2 -to-sp3 hybridization transformation has been exclusively observed in covalent or molecular crystals overwhelmingly above ≈10 GPa, and the approaches to lower the transition pressure are limited on external heat-treatment and/or catalyzers. Herein we demonstrate that, by internal-lattice stress-transfer from ionic to covalent groups, the transformation can be significantly prompted, as shown in a crystal of LiBO2 under 2.85 GPa for the first case in ionic crystals. This unprecedentedly low transformation pressure is ascribed to the enhanced localized stress on covalent B-O frames transferred from ionic Li-O bonds in LiBO2 , and accordingly the corresponding structural feature is summarized. This work provides an internal structural regulation strategy for pressure-reduction of the s-p orbital hybridization transformation and extends the sp1 /sp2 -to-sp3 transformation landscape from molecular and covalent compounds to ionic systems.

By date By citations

Citations by journals

	1
Journal of the American Chemical Society	Journal of the American Chemical Society, 1, 50% Journal of the American Chemical Society 1 publication, 50%
Chemistry - A European Journal	Chemistry - A European Journal, 1, 50% Chemistry - A European Journal 1 publication, 50%
	1

Citations by publishers

	1
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 50% American Chemical Society (ACS) 1 publication, 50%
Wiley	Wiley, 1, 50% Wiley 1 publication, 50%
	1

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2023],"ids":[0],"codes":[0],"imageUrls":[""],"datasets":[{"label":"Citations number","data":[2],"backgroundColor":["#3B82F6"],"percentage":["100"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of the American Chemical Society","Chemistry - A European Journal"],"ids":[4813,24708],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[1,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[50,50],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Wiley"],"ids":[40,11],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[1,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[50,50],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Metrics

Cite this

GOST |

Cite this

GOST Copy

Jiang X. et al. sp 2 to sp 3 Hybridization Transformation in Ionic Crystals under Unprecedentedly Low Pressure // Angewandte Chemie - International Edition. 2022.

GOST all authors (up to 50) Copy

Jiang X., Molokeev M. S., Wang N., Wang Y., Wen T., Zhichao D., Liu Y., Li W., Lin Z. sp 2 to sp 3 Hybridization Transformation in Ionic Crystals under Unprecedentedly Low Pressure // Angewandte Chemie - International Edition. 2022.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1002/anie.202208247

UR - https://doi.org/10.1002%2Fanie.202208247

TI - sp 2 to sp 3 Hybridization Transformation in Ionic Crystals under Unprecedentedly Low Pressure

T2 - Angewandte Chemie - International Edition

AU - Jiang, Xingxing

AU - Molokeev, Maxim S.

AU - Wang, Naizheng

AU - Wang, Yonggang

AU - Wen, Ting

AU - Zhichao, Dong

AU - Liu, Youquan

AU - Li, Wei

AU - Lin, Zheshuai

PY - 2022

DA - 2022/09/29 00:00:00

PB - Wiley

SN - 1433-7851

SN - 1521-3773

ER -

BibTex

Cite this

BibTex Copy

@article{2022_Jiang,

author = {Xingxing Jiang and Maxim S. Molokeev and Naizheng Wang and Yonggang Wang and Ting Wen and Dong Zhichao and Youquan Liu and Wei Li and Zheshuai Lin},

title = {sp 2 to sp 3 Hybridization Transformation in Ionic Crystals under Unprecedentedly Low Pressure},

journal = {Angewandte Chemie - International Edition},

year = {2022},

publisher = {Wiley},

month = {sep},

url = {https://doi.org/10.1002%2Fanie.202208247},

doi = {10.1002/anie.202208247}

}

Found error?

Publisher

Wiley

Journal

Angewandte Chemie - International Edition

Quartile SCImago

Quartile WOS

Impact factor

16.6

ISSN

14337851 (Print)
15213773 (Electronic)