Photocatalytic Direct Decarboxylation of Carboxylic Acids to Derivatize or Degrade Polymers

Publication typeJournal Article
Publication date2022-09-05
scimago Q1
wos Q1
SJR5.550
CiteScore27.6
Impact factor16.9
ISSN14337851, 15213773
General Chemistry
Catalysis
Abstract
Visible light-driven direct decarboxylation of carboxylic acid side chains in macromolecules was explored as a robust post-polymerization modification strategy. Multiple transformations of copolymers were achieved, including derivatization with olefin units, functionalization with pendent alkenes, and backbone degradation. These decarboxylative processes were rapid, selective, and displayed high atom economy.
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GOST Copy
Adili A. et al. Photocatalytic Direct Decarboxylation of Carboxylic Acids to Derivatize or Degrade Polymers // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 40.
GOST all authors (up to 50) Copy
Adili A., Korpusik A. B., Seidel D., Sumerlin B. S. Photocatalytic Direct Decarboxylation of Carboxylic Acids to Derivatize or Degrade Polymers // Angewandte Chemie - International Edition. 2022. Vol. 61. No. 40.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/anie.202209085
UR - https://doi.org/10.1002/anie.202209085
TI - Photocatalytic Direct Decarboxylation of Carboxylic Acids to Derivatize or Degrade Polymers
T2 - Angewandte Chemie - International Edition
AU - Adili, Alafate
AU - Korpusik, Angie B
AU - Seidel, Daniel
AU - Sumerlin, Brent S.
PY - 2022
DA - 2022/09/05
PB - Wiley
IS - 40
VL - 61
PMID - 35989222
SN - 1433-7851
SN - 1521-3773
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Adili,
author = {Alafate Adili and Angie B Korpusik and Daniel Seidel and Brent S. Sumerlin},
title = {Photocatalytic Direct Decarboxylation of Carboxylic Acids to Derivatize or Degrade Polymers},
journal = {Angewandte Chemie - International Edition},
year = {2022},
volume = {61},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/anie.202209085},
number = {40},
doi = {10.1002/anie.202209085}
}