Angewandte Chemie - International Edition, volume 62, issue 29
Cu‐bound formates are main reaction intermediates during CO2 hydrogenation to methanol over Cu/ZrO2
1
Univ Lyon Université Claude Bernard Lyon, CNRS, IRCELYON 2 Av. Albert Einstein 69626 Villeurbanne France
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Publication type: Journal Article
Publication date: 2023-06-12
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 16.6
ISSN: 14337851, 15213773
General Chemistry
Catalysis
Abstract
Cu/ZrO2 is a promising catalyst for the hydrogenation of CO2 to methanol. Reaction pathways involving formates or hydroxycarbonyls have been proposed. We show here that three different types of formates can be observed under reaction conditions at 220 °C and 3 bar, one being located on metallic Cu and two others being bound to ZrO2. The surface concentrations of formates were determined through calibration curves and their reactivity measured during chemical transient experiments. The Cu‐bound formate represented only about 7 % of surface formates, but exhibited a higher reactivity and was found to be the only formate that could account for all the production of methanol. Copper is thus not there only to activate H2, but also bears other crucial intermediates. This work reemphasizes that fully quantitative IR analyses and transient methods are required to unravel the role of surface species.
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- We do not take into account publications without a DOI.
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Meunier F. A. et al. Cu‐bound formates are main reaction intermediates during CO2 hydrogenation to methanol over Cu/ZrO2 // Angewandte Chemie - International Edition. 2023. Vol. 62. No. 29.
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Meunier F. A., Dansette I., Paredes-Nunez A., Schuurman Y. Cu‐bound formates are main reaction intermediates during CO2 hydrogenation to methanol over Cu/ZrO2 // Angewandte Chemie - International Edition. 2023. Vol. 62. No. 29.
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TY - JOUR
DO - 10.1002/anie.202303939
UR - https://doi.org/10.1002/anie.202303939
TI - Cu‐bound formates are main reaction intermediates during CO2 hydrogenation to methanol over Cu/ZrO2
T2 - Angewandte Chemie - International Edition
AU - Meunier, F. A.
AU - Dansette, Isaac
AU - Paredes-Nunez, Anaelle
AU - Schuurman, Yves
PY - 2023
DA - 2023/06/12 00:00:00
PB - Wiley
IS - 29
VL - 62
SN - 1433-7851
SN - 1521-3773
ER -
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@article{2023_Meunier,
author = {F. A. Meunier and Isaac Dansette and Anaelle Paredes-Nunez and Yves Schuurman},
title = {Cu‐bound formates are main reaction intermediates during CO2 hydrogenation to methanol over Cu/ZrO2},
journal = {Angewandte Chemie - International Edition},
year = {2023},
volume = {62},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/anie.202303939},
number = {29},
doi = {10.1002/anie.202303939}
}