Applied Organometallic Chemistry, volume 5, issue 3, pages 191-194

Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts

Witold Kuran 1
1
 
Faculty of Chemistry, Technical University (
Publication typeJournal Article
Publication date1991-05-01
Q2
Q2
SJR0.557
CiteScore7.8
Impact factor3.7
ISSN02682605, 10990739
General Chemistry
Inorganic Chemistry
Abstract
Reaction of carbon dioxide with propylene oxide in the presence of catalysts with condensed zinc species (derived from diethylzinc and dihydric phenols, e.g. catechol o-C 6 H 4 (OH) 2 and saligenin o-HOC 6 H 4 CH 2 OH) yields poly(propylene carbonate) as well as propylene carbonate. The above reaction in the presence of catalysts with noncondensed zinc species (derived from diethylzinc and phenol) yields propylene carbonate as the main product, but in relatively low yield. The mechanism of the linear and cyclic carbonate formation is discussed in terms of the nature of the catalyst's active sites for both types
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GOST Copy
Kuran W. Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts // Applied Organometallic Chemistry. 1991. Vol. 5. No. 3. pp. 191-194.
GOST all authors (up to 50) Copy
Kuran W. Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts // Applied Organometallic Chemistry. 1991. Vol. 5. No. 3. pp. 191-194.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/aoc.590050308
UR - https://doi.org/10.1002/aoc.590050308
TI - Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts
T2 - Applied Organometallic Chemistry
AU - Kuran, Witold
PY - 1991
DA - 1991/05/01
PB - Wiley
SP - 191-194
IS - 3
VL - 5
SN - 0268-2605
SN - 1099-0739
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1991_Kuran,
author = {Witold Kuran},
title = {Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts},
journal = {Applied Organometallic Chemistry},
year = {1991},
volume = {5},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/aoc.590050308},
number = {3},
pages = {191--194},
doi = {10.1002/aoc.590050308}
}
MLA
Cite this
MLA Copy
Kuran, Witold. “Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts.” Applied Organometallic Chemistry, vol. 5, no. 3, May. 1991, pp. 191-194. https://doi.org/10.1002/aoc.590050308.
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