Applied Organometallic Chemistry, volume 5, issue 3, pages 191-194
Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts
1
Faculty of Chemistry, Technical University (
Publication type: Journal Article
Publication date: 1991-05-01
Journal:
Applied Organometallic Chemistry
Q2
Q2
SJR: 0.557
CiteScore: 7.8
Impact factor: 3.7
ISSN: 02682605, 10990739
General Chemistry
Inorganic Chemistry
Abstract
Reaction of carbon dioxide with propylene oxide in the presence of catalysts with condensed zinc species (derived from diethylzinc and dihydric phenols, e.g. catechol o-C 6 H 4 (OH) 2 and saligenin o-HOC 6 H 4 CH 2 OH) yields poly(propylene carbonate) as well as propylene carbonate. The above reaction in the presence of catalysts with noncondensed zinc species (derived from diethylzinc and phenol) yields propylene carbonate as the main product, but in relatively low yield. The mechanism of the linear and cyclic carbonate formation is discussed in terms of the nature of the catalyst's active sites for both types
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GOST
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Kuran W. Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts // Applied Organometallic Chemistry. 1991. Vol. 5. No. 3. pp. 191-194.
GOST all authors (up to 50)
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Kuran W. Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts // Applied Organometallic Chemistry. 1991. Vol. 5. No. 3. pp. 191-194.
Cite this
RIS
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TY - JOUR
DO - 10.1002/aoc.590050308
UR - https://doi.org/10.1002/aoc.590050308
TI - Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts
T2 - Applied Organometallic Chemistry
AU - Kuran, Witold
PY - 1991
DA - 1991/05/01
PB - Wiley
SP - 191-194
IS - 3
VL - 5
SN - 0268-2605
SN - 1099-0739
ER -
Cite this
BibTex (up to 50 authors)
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@article{1991_Kuran,
author = {Witold Kuran},
title = {Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts},
journal = {Applied Organometallic Chemistry},
year = {1991},
volume = {5},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/aoc.590050308},
number = {3},
pages = {191--194},
doi = {10.1002/aoc.590050308}
}
Cite this
MLA
Copy
Kuran, Witold. “Active sites, nature and mechanism of carbon dioxide?propylene oxide copolymerization and cyclization reactions employing organozinc?oxygen catalysts.” Applied Organometallic Chemistry, vol. 5, no. 3, May. 1991, pp. 191-194. https://doi.org/10.1002/aoc.590050308.