Wiley
Chemistry - An Asian Journal
,  том 10 ,  издание 8 ,  страницы 1622-1625

Capturing C90 Isomers as CF3 Derivatives: C90(30)(CF3)14, C90(35)(CF3)16/18, and C90(45)(CF3)16/18

Тип публикации: Journal Article
Дата публикации: 2015-06-25
Wiley
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wos Q2
БС1
SJR: 0.751
CiteScore: 5.9
Impact factor: 3.3
ISSN: 18614728, 1861471X
General Chemistry
Organic Chemistry
Biochemistry
Краткое описание

High‐temperature trifluoromethylation of a C90 isomeric mixture with CF3I followed by HPLC separation of C90(CF3)n isomers resulted in the isolation of several individual C90(CF3)14−18 compounds. Single crystal X‐ray diffraction with the use of synchrotron radiation resulted in the structure determination of C90(30)(CF3)14, C90(35)(CF3)16/18, and C90(45)(CF3)16/18. Their addition patterns are discussed and compared with the known isomers C90(30)(CF3)18 and C90(35)(CF3)14, respectively. The presence of the most stable C90 isomer, C90(45), in the fullerene soot has been confirmed for the first time.

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Tamm N. B., Troyanov S. Capturing C90 Isomers as CF3 Derivatives: C90(30)(CF3)14, C90(35)(CF3)16/18, and C90(45)(CF3)16/18 // Chemistry - An Asian Journal. 2015. Vol. 10. No. 8. pp. 1622-1625.
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Tamm N. B., Troyanov S. Capturing C90 Isomers as CF3 Derivatives: C90(30)(CF3)14, C90(35)(CF3)16/18, and C90(45)(CF3)16/18 // Chemistry - An Asian Journal. 2015. Vol. 10. No. 8. pp. 1622-1625.
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TY - JOUR
DO - 10.1002/asia.201500521
UR - https://onlinelibrary.wiley.com/doi/10.1002/asia.201500521
TI - Capturing C90 Isomers as CF3 Derivatives: C90(30)(CF3)14, C90(35)(CF3)16/18, and C90(45)(CF3)16/18
T2 - Chemistry - An Asian Journal
AU - Tamm, Nadezhda B
AU - Troyanov, Sergey
PY - 2015
DA - 2015/06/25
PB - Wiley
SP - 1622-1625
IS - 8
VL - 10
PMID - 26097124
SN - 1861-4728
SN - 1861-471X
ER -
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@article{2015_Tamm,
author = {Nadezhda B Tamm and Sergey Troyanov},
title = {Capturing C90 Isomers as CF3 Derivatives: C90(30)(CF3)14, C90(35)(CF3)16/18, and C90(45)(CF3)16/18},
journal = {Chemistry - An Asian Journal},
year = {2015},
volume = {10},
publisher = {Wiley},
month = {jun},
url = {https://onlinelibrary.wiley.com/doi/10.1002/asia.201500521},
number = {8},
pages = {1622--1625},
doi = {10.1002/asia.201500521}
}
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Tamm, Nadezhda B., and Sergey Troyanov. “Capturing C90 Isomers as CF3 Derivatives: C90(30)(CF3)14, C90(35)(CF3)16/18, and C90(45)(CF3)16/18.” Chemistry - An Asian Journal, vol. 10, no. 8, Jun. 2015, pp. 1622-1625. https://onlinelibrary.wiley.com/doi/10.1002/asia.201500521.