Highly Regio‐ and Stereoselective Hydrosilylation of Alkynes Catalyzed by Tridentate Cobalt Complexes
Publication type: Journal Article
Publication date: 2019-07-08
scimago Q2
wos Q2
SJR: 0.751
CiteScore: 5.9
Impact factor: 3.3
ISSN: 18614728, 1861471X
PubMed ID:
31140204
General Chemistry
Organic Chemistry
Biochemistry
Abstract
Several cobalt complexes bearing tridentate (NNN) ligands were synthesized and served as precatalysts for alkyne hydrosilylation with Ph2 SiH2 . For terminal alkynes, the catalyst L2 b-CoCl2 was selected, and resulted in the corresponding α-vinylsilanes with high (Markovnikov) regioselectivity and extensive functional-group tolerance. For internal diaryl alkynes, the catalyst L2 c-CoCl2 exhibited the best activity, and afforded E-selective vinylsilanes through syn-addition in excellent yield under mild conditions.
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35
Total citations:
35
Citations from 2024:
7
(20%)
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GOST
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Kong D., Hu B., Chen D. Highly Regio‐ and Stereoselective Hydrosilylation of Alkynes Catalyzed by Tridentate Cobalt Complexes // Chemistry - An Asian Journal. 2019. Vol. 14. No. 15. pp. 2694-2703.
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Kong D., Hu B., Chen D. Highly Regio‐ and Stereoselective Hydrosilylation of Alkynes Catalyzed by Tridentate Cobalt Complexes // Chemistry - An Asian Journal. 2019. Vol. 14. No. 15. pp. 2694-2703.
Cite this
RIS
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TY - JOUR
DO - 10.1002/asia.201900577
UR - https://doi.org/10.1002/asia.201900577
TI - Highly Regio‐ and Stereoselective Hydrosilylation of Alkynes Catalyzed by Tridentate Cobalt Complexes
T2 - Chemistry - An Asian Journal
AU - Kong, Degong
AU - Hu, Bowen
AU - Chen, Dafa
PY - 2019
DA - 2019/07/08
PB - Wiley
SP - 2694-2703
IS - 15
VL - 14
PMID - 31140204
SN - 1861-4728
SN - 1861-471X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Kong,
author = {Degong Kong and Bowen Hu and Dafa Chen},
title = {Highly Regio‐ and Stereoselective Hydrosilylation of Alkynes Catalyzed by Tridentate Cobalt Complexes},
journal = {Chemistry - An Asian Journal},
year = {2019},
volume = {14},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/asia.201900577},
number = {15},
pages = {2694--2703},
doi = {10.1002/asia.201900577}
}
Cite this
MLA
Copy
Kong, Degong, et al. “Highly Regio‐ and Stereoselective Hydrosilylation of Alkynes Catalyzed by Tridentate Cobalt Complexes.” Chemistry - An Asian Journal, vol. 14, no. 15, Jul. 2019, pp. 2694-2703. https://doi.org/10.1002/asia.201900577.