Interpretation of Counterion Spin Relaxation in Polyelectrolyte Solutions. II. Effects of Finite Polyion Length
Publication type: Journal Article
Publication date: 1985-12-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00059021
General Chemical Engineering
Abstract
The applicability of the recently proposed CDM theory of counterion spin relaxation in polyelectrolyte solutions [Halle, Wennerstrom & Piculell, J. Phys. Chem. 88, 2482 (1984)] is extended to low degrees of polymerization. Polyion end effects on the counterion distribution and dynamics are described in the spheroidal-cell model of Bratko & Dolar [J. Chem. Phys. 80, 5782 (1984)]. The extended theory is applied to 23Na spin relaxation data from saltfree solutions of sodium poly (styrenesulfonate) and it is found that the available data can be explained by a model in which polyions of length 20–100nm reorient as fully extended, rigid bodies.
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Total citations:
13
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Halle B., Bratko D., Piculell L. Interpretation of Counterion Spin Relaxation in Polyelectrolyte Solutions. II. Effects of Finite Polyion Length // Berichte der Bunsengesellschaft für physikalische Chemie. 1985. Vol. 89. No. 12. pp. 1254-1260.
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Halle B., Bratko D., Piculell L. Interpretation of Counterion Spin Relaxation in Polyelectrolyte Solutions. II. Effects of Finite Polyion Length // Berichte der Bunsengesellschaft für physikalische Chemie. 1985. Vol. 89. No. 12. pp. 1254-1260.
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RIS
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TY - JOUR
DO - 10.1002/bbpc.19850891204
UR - https://doi.org/10.1002/bbpc.19850891204
TI - Interpretation of Counterion Spin Relaxation in Polyelectrolyte Solutions. II. Effects of Finite Polyion Length
T2 - Berichte der Bunsengesellschaft für physikalische Chemie
AU - Halle, Bertil
AU - Bratko, Dusan
AU - Piculell, Lennart
PY - 1985
DA - 1985/12/01
PB - Wiley
SP - 1254-1260
IS - 12
VL - 89
SN - 0005-9021
ER -
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BibTex (up to 50 authors)
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@article{1985_Halle,
author = {Bertil Halle and Dusan Bratko and Lennart Piculell},
title = {Interpretation of Counterion Spin Relaxation in Polyelectrolyte Solutions. II. Effects of Finite Polyion Length},
journal = {Berichte der Bunsengesellschaft für physikalische Chemie},
year = {1985},
volume = {89},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/bbpc.19850891204},
number = {12},
pages = {1254--1260},
doi = {10.1002/bbpc.19850891204}
}
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MLA
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Halle, Bertil, et al. “Interpretation of Counterion Spin Relaxation in Polyelectrolyte Solutions. II. Effects of Finite Polyion Length.” Berichte der Bunsengesellschaft für physikalische Chemie, vol. 89, no. 12, Dec. 1985, pp. 1254-1260. https://doi.org/10.1002/bbpc.19850891204.