Nickel Salicylideniminato 1D MOFs via Electrochemical Polymerization
Polymers derived from nickel complexes of salicylaldimines are extensively studied due to their electrochemical, catalytic, and sensing properties. However, almost all studies are devoted to the polymers obtained from tetradentate bis(salicylidenaldiminato) complexes, in which the aromatic rings are bound via an imine bridge. Herein, we report a first systematic study focused on the polymerization of salicylaldimine nickel complexes without a bridge between the imine fragments. As a result, an impact of the ligand structure on the polymerization ability of the complexes and electrochemical behavior of the polymers obtained thereof was discovered and quantified. An observed phenomenon was rationalized both computationally and experimentally, involving the electrochemical and spectroelectrochemical techniques.
Citations by journals
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Journal of Electroanalytical Chemistry
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Journal of Electroanalytical Chemistry
1 publication, 25%
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Electrochimica Acta
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Electrochimica Acta
1 publication, 25%
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Journal of Molecular Structure
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Journal of Molecular Structure
1 publication, 25%
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Inorganic Chemistry
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Inorganic Chemistry
1 publication, 25%
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1
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Citations by publishers
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Elsevier
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Elsevier
3 publications, 75%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
1 publication, 25%
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