Remarkable ligand effect in Ni- And Pd-catalyzed bisthiolation and bisselenation of terminal alkynes: Solving the problem of stereoselective dialkyldichalcogenide addition to the C≡C bond
Publication type: Journal Article
Publication date: 2008-03-07
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
18213556
General Chemistry
Catalysis
Organic Chemistry
Abstract
We have developed two new catalytic systems based on Ni and Pd complexes to solve the challenging problem of dialkyldichalcogenide (Alk2E2; E=S, Se) addition to alkynes. A comparative study of two catalytic systems-Ni/PMe2Ph and Pd/PCy2Ph-has revealed that the Ni catalyst is superior with respect to high catalytic activity and more general scope relative to the Pd system. A novel synthetic methodology was developed for the preparation of (Z)-bis(alkylthio)alkenes and (Z)-bis(alkylseleno)alkenes from terminal alkynes with excellent stereoselectivity and high yields.
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79
Total citations:
79
Citations from 2025:
5
(6.33%)
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GOST
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Ananikov V. P. et al. Remarkable ligand effect in Ni- And Pd-catalyzed bisthiolation and bisselenation of terminal alkynes: Solving the problem of stereoselective dialkyldichalcogenide addition to the C≡C bond // Chemistry - A European Journal. 2008. Vol. 14. No. 8. pp. 2420-2434.
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Ananikov V. P., Gayduk K. A., Beletskaya I. P., Khrustalev V. N., Antipin M. Y. Remarkable ligand effect in Ni- And Pd-catalyzed bisthiolation and bisselenation of terminal alkynes: Solving the problem of stereoselective dialkyldichalcogenide addition to the C≡C bond // Chemistry - A European Journal. 2008. Vol. 14. No. 8. pp. 2420-2434.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.200701278
UR - https://doi.org/10.1002/chem.200701278
TI - Remarkable ligand effect in Ni- And Pd-catalyzed bisthiolation and bisselenation of terminal alkynes: Solving the problem of stereoselective dialkyldichalcogenide addition to the C≡C bond
T2 - Chemistry - A European Journal
AU - Ananikov, Valentine P.
AU - Gayduk, Konstantin A
AU - Beletskaya, Irina P.
AU - Khrustalev, Victor N.
AU - Antipin, Mikhail Yu.
PY - 2008
DA - 2008/03/07
PB - Wiley
SP - 2420-2434
IS - 8
VL - 14
PMID - 18213556
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
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@article{2008_Ananikov,
author = {Valentine P. Ananikov and Konstantin A Gayduk and Irina P. Beletskaya and Victor N. Khrustalev and Mikhail Yu. Antipin},
title = {Remarkable ligand effect in Ni- And Pd-catalyzed bisthiolation and bisselenation of terminal alkynes: Solving the problem of stereoselective dialkyldichalcogenide addition to the C≡C bond},
journal = {Chemistry - A European Journal},
year = {2008},
volume = {14},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/chem.200701278},
number = {8},
pages = {2420--2434},
doi = {10.1002/chem.200701278}
}
Cite this
MLA
Copy
Ananikov, Valentine P., et al. “Remarkable ligand effect in Ni- And Pd-catalyzed bisthiolation and bisselenation of terminal alkynes: Solving the problem of stereoselective dialkyldichalcogenide addition to the C≡C bond.” Chemistry - A European Journal, vol. 14, no. 8, Mar. 2008, pp. 2420-2434. https://doi.org/10.1002/chem.200701278.
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