Chemistry - A European Journal, volume 14, issue 30, pages 9330-9337

Is the Hoveyda-Grubbs Complex a Vinylogous Fischer-Type Carbene? Aromaticity-Controlled Activity of Ruthenium Metathesis Catalysts

Michał Barbasiewicz 1, 2
Anna Szadkowska 2
Anna Makal 3
Katarzyna Natalia Jarzembska 3
Krzysztof Woźniak 3
Publication typeJournal Article
Publication date2008-10-20
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor4.3
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
Aromaticity [Ru]les! Novel benzoanalogues of the Hoveyda–Grubbs metathesis catalyst exhibit unexpected differences in reactivity (see scheme). Structural studies and topological analyses reveal that aromatic conjugation within the ruthenium chelate ring, which is governed by the ligand core, is a source of this phenomenon. The concept explains properties of 2-alkoxybenzylidene ligands and their substituent effects in metathesis catalysts.

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GOST |
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GOST Copy
Barbasiewicz M. et al. Is the Hoveyda-Grubbs Complex a Vinylogous Fischer-Type Carbene? Aromaticity-Controlled Activity of Ruthenium Metathesis Catalysts // Chemistry - A European Journal. 2008. Vol. 14. No. 30. pp. 9330-9337.
GOST all authors (up to 50) Copy
Barbasiewicz M., Szadkowska A., Makal A., Jarzembska K. N., Woźniak K., Grela K. Is the Hoveyda-Grubbs Complex a Vinylogous Fischer-Type Carbene? Aromaticity-Controlled Activity of Ruthenium Metathesis Catalysts // Chemistry - A European Journal. 2008. Vol. 14. No. 30. pp. 9330-9337.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/chem.200800704
UR - https://doi.org/10.1002/chem.200800704
TI - Is the Hoveyda-Grubbs Complex a Vinylogous Fischer-Type Carbene? Aromaticity-Controlled Activity of Ruthenium Metathesis Catalysts
T2 - Chemistry - A European Journal
AU - Barbasiewicz, Michał
AU - Szadkowska, Anna
AU - Makal, Anna
AU - Jarzembska, Katarzyna Natalia
AU - Woźniak, Krzysztof
AU - Grela, Karol
PY - 2008
DA - 2008/10/20 00:00:00
PB - Wiley
SP - 9330-9337
IS - 30
VL - 14
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
Cite this
BibTex Copy
@article{2008_Barbasiewicz,
author = {Michał Barbasiewicz and Anna Szadkowska and Anna Makal and Katarzyna Natalia Jarzembska and Krzysztof Woźniak and Karol Grela},
title = {Is the Hoveyda-Grubbs Complex a Vinylogous Fischer-Type Carbene? Aromaticity-Controlled Activity of Ruthenium Metathesis Catalysts},
journal = {Chemistry - A European Journal},
year = {2008},
volume = {14},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/chem.200800704},
number = {30},
pages = {9330--9337},
doi = {10.1002/chem.200800704}
}
MLA
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MLA Copy
Barbasiewicz, Michał, et al. “Is the Hoveyda-Grubbs Complex a Vinylogous Fischer-Type Carbene? Aromaticity-Controlled Activity of Ruthenium Metathesis Catalysts.” Chemistry - A European Journal, vol. 14, no. 30, Oct. 2008, pp. 9330-9337. https://doi.org/10.1002/chem.200800704.
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