Chemistry - A European Journal, volume 15, issue 21, pages 5208-5211

Rh^I-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones

Yanqing Zhang ¹

Zuliang Chen ¹

Yuanjing Xiao ¹

Junliang Zhang ^{2, 3}

Hide authors affiliations Show authors affiliations: 3 affiliations

Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, P.R. China, Fax: (+86) 21-6223-3213 |

Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062 (P.R. China), Fax: (+86) 21-6223-3213 |

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, (P.R. China) |

Publication type: Journal Article

Publication date: 2009-05-18

Wiley

Journal: Chemistry - A European Journal

SJR: 1.058

CiteScore: 7.9

Impact factor: 3.9

ISSN: 09476539, 15213765

DOI: 10.1002/chem.200900413

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General Chemistry

Catalysis

Organic Chemistry

Abstract

Efficient route: A novel Rh(I)-catalyzed regio- and stereospecific carbonylation reaction of (1-alkynyl)cyclopropyl ketones by selective activation of a carbon-carbon sigma bond of the cyclopropane ring was demonstrated (see scheme). This method provides a general, efficient, stereoselective route to synthesise 1,3,5-trisubstituted and 1,3,5,6-tetrasubstituted 5,6-dihydrocyclopenta[c]furan-4-one with convertible functional groups.

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GOST |

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GOST Copy

Zhang Y. et al. RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones // Chemistry - A European Journal. 2009. Vol. 15. No. 21. pp. 5208-5211.

GOST all authors (up to 50) Copy

Zhang Y., Chen Z., Xiao Y., Zhang J. RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones // Chemistry - A European Journal. 2009. Vol. 15. No. 21. pp. 5208-5211.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/chem.200900413

UR - https://doi.org/10.1002/chem.200900413

TI - RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones

T2 - Chemistry - A European Journal

AU - Zhang, Yanqing

AU - Chen, Zuliang

AU - Xiao, Yuanjing

AU - Zhang, Junliang

PY - 2009

DA - 2009/05/18

PB - Wiley

SP - 5208-5211

IS - 21

VL - 15

SN - 0947-6539

SN - 1521-3765

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2009_Zhang,

author = {Yanqing Zhang and Zuliang Chen and Yuanjing Xiao and Junliang Zhang},

title = {RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones},

journal = {Chemistry - A European Journal},

year = {2009},

volume = {15},

publisher = {Wiley},

month = {may},

url = {https://doi.org/10.1002/chem.200900413},

number = {21},

pages = {5208--5211},

doi = {10.1002/chem.200900413}

}

MLA

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MLA Copy

Zhang, Yanqing, et al. “RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones.” Chemistry - A European Journal, vol. 15, no. 21, May. 2009, pp. 5208-5211. https://doi.org/10.1002/chem.200900413.

Found error?

Publisher

Wiley

Journal

Chemistry - A European Journal

SJR

1.058

CiteScore

7.9

Impact factor

3.9

ISSN

09476539 (Print)

15213765 (Electronic)