RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones
Publication type: Journal Article
Publication date: 2009-05-18
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
19360828
General Chemistry
Catalysis
Organic Chemistry
Abstract
Efficient route: A novel Rh(I)-catalyzed regio- and stereospecific carbonylation reaction of (1-alkynyl)cyclopropyl ketones by selective activation of a carbon-carbon sigma bond of the cyclopropane ring was demonstrated (see scheme). This method provides a general, efficient, stereoselective route to synthesise 1,3,5-trisubstituted and 1,3,5,6-tetrasubstituted 5,6-dihydrocyclopenta[c]furan-4-one with convertible functional groups.
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77
Total citations:
77
Citations from 2024:
6
(7%)
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GOST
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Zhang Y. et al. RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones // Chemistry - A European Journal. 2009. Vol. 15. No. 21. pp. 5208-5211.
GOST all authors (up to 50)
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Zhang Y., Chen Z., Xiao Y., Zhang J. RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones // Chemistry - A European Journal. 2009. Vol. 15. No. 21. pp. 5208-5211.
Cite this
RIS
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TY - JOUR
DO - 10.1002/chem.200900413
UR - https://doi.org/10.1002/chem.200900413
TI - RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones
T2 - Chemistry - A European Journal
AU - Zhang, Yanqing
AU - Chen, Zuliang
AU - Xiao, Yuanjing
AU - Zhang, Junliang
PY - 2009
DA - 2009/05/18
PB - Wiley
SP - 5208-5211
IS - 21
VL - 15
PMID - 19360828
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
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@article{2009_Zhang,
author = {Yanqing Zhang and Zuliang Chen and Yuanjing Xiao and Junliang Zhang},
title = {RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones},
journal = {Chemistry - A European Journal},
year = {2009},
volume = {15},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/chem.200900413},
number = {21},
pages = {5208--5211},
doi = {10.1002/chem.200900413}
}
Cite this
MLA
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Zhang, Yanqing, et al. “RhI-Catalyzed Regio- and Stereospecific Carbonylation of 1-(1-Alkynyl)cyclopropyl Ketones: A Modular Entry to Highly Substituted 5,6-Dihydrocyclopenta[c]furan-4-ones.” Chemistry - A European Journal, vol. 15, no. 21, May. 2009, pp. 5208-5211. https://doi.org/10.1002/chem.200900413.