Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base
Publication type: Journal Article
Publication date: 2011-01-17
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
21319240
General Chemistry
Catalysis
Organic Chemistry
Abstract
Three roles for hydroxide: The base OH− plays a triple role in Suzuki–Miyaura reactions (see graphic): 1) formation of [ArPd(OH)(PPh3)2] as the reactive species involved in the rate-determining transmetalation, 2) formation of unreactive Ar′B(OH)3− by reaction of OH− with ArB(OH)2, and 3) unexpected acceleration of the reductive elimination by reaction of OH− with the intermediate trans-[ArPdAr′(PPh3)2].
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338
Total citations:
338
Citations from 2025:
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(3.25%)
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Amatore C., Jutand A., Le Duc G. Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base // Chemistry - A European Journal. 2011. Vol. 17. No. 8. pp. 2492-2503.
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Amatore C., Jutand A., Le Duc G. Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base // Chemistry - A European Journal. 2011. Vol. 17. No. 8. pp. 2492-2503.
Cite this
RIS
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TY - JOUR
DO - 10.1002/chem.201001911
UR - https://doi.org/10.1002/chem.201001911
TI - Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base
T2 - Chemistry - A European Journal
AU - Amatore, Christian
AU - Jutand, Anny
AU - Le Duc, Gaëtan
PY - 2011
DA - 2011/01/17
PB - Wiley
SP - 2492-2503
IS - 8
VL - 17
PMID - 21319240
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
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@article{2011_Amatore,
author = {Christian Amatore and Anny Jutand and Gaëtan Le Duc},
title = {Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base},
journal = {Chemistry - A European Journal},
year = {2011},
volume = {17},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/chem.201001911},
number = {8},
pages = {2492--2503},
doi = {10.1002/chem.201001911}
}
Cite this
MLA
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Amatore, Christian, et al. “Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base.” Chemistry - A European Journal, vol. 17, no. 8, Jan. 2011, pp. 2492-2503. https://doi.org/10.1002/chem.201001911.