Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity
Publication type: Journal Article
Publication date: 2012-01-20
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
22262651
General Chemistry
Catalysis
Organic Chemistry
Abstract
Cyclopropane rings true: By selecting the appropriate substituents on the ester and silyl groups, fused cyclopentane derivatives with multiple contiguous stereocenters can be synthesized with excellent diastereoselectivity through Cu(II)/bisoxazoline-catalyzed intermolecular [3+2] cycloaddition reactions of cyclopropane-1,1-dicarboxylates and cyclic enol silyl ethers (see scheme).
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83
Total citations:
83
Citations from 2025:
3
(3.61%)
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GOST
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QU J. et al. Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity // Chemistry - A European Journal. 2012. Vol. 18. No. 8. pp. 2196-2201.
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QU J., Liang Y., Xu H., Sun X., Yu Z., Tang Y. Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity // Chemistry - A European Journal. 2012. Vol. 18. No. 8. pp. 2196-2201.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201103495
UR - https://doi.org/10.1002/chem.201103495
TI - Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity
T2 - Chemistry - A European Journal
AU - QU, JIANPING
AU - Liang, Yong
AU - Xu, Hao
AU - Sun, Xiuli
AU - Yu, Zhi-Xiang
AU - Tang, Yong
PY - 2012
DA - 2012/01/20
PB - Wiley
SP - 2196-2201
IS - 8
VL - 18
PMID - 22262651
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_QU,
author = {JIANPING QU and Yong Liang and Hao Xu and Xiuli Sun and Zhi-Xiang Yu and Yong Tang},
title = {Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity},
journal = {Chemistry - A European Journal},
year = {2012},
volume = {18},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/chem.201103495},
number = {8},
pages = {2196--2201},
doi = {10.1002/chem.201103495}
}
Cite this
MLA
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QU, JIANPING, et al. “Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity.” Chemistry - A European Journal, vol. 18, no. 8, Jan. 2012, pp. 2196-2201. https://doi.org/10.1002/chem.201103495.