CO Versus CC Bond Cleavage: Selectivity Control in Lewis Acid Catalyzed Chemodivergent Cycloadditions of Aryl Oxiranyldicarboxylates with Aldehydes, and Theoretical Rationalizations of Reaction Pathways
Publication type: Journal Article
Publication date: 2012-06-11
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
22689542
General Chemistry
Catalysis
Organic Chemistry
Abstract
A clean break: Lewis acid catalyzed chemodivergent [3+2] cycloadditions of aryl oxiranyldicarboxylates with aldehydes are revealed, in which the CC or CO bond cleavage of oxiranes can be controlled by the use of Ni(ClO4)2 or Sn(OTf)2 catalysts (see scheme). Possible reaction pathways for these transformations are demonstrated by theoretical calculations.
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Metrics
66
Total citations:
66
Citations from 2025:
4
(6.06%)
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GOST
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Chen Z. et al. CO Versus CC Bond Cleavage: Selectivity Control in Lewis Acid Catalyzed Chemodivergent Cycloadditions of Aryl Oxiranyldicarboxylates with Aldehydes, and Theoretical Rationalizations of Reaction Pathways // Chemistry - A European Journal. 2012. Vol. 18. No. 28. pp. 8591-8595.
GOST all authors (up to 50)
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Chen Z., Tian Z., Zhang J., Ma J., Zhang J. CO Versus CC Bond Cleavage: Selectivity Control in Lewis Acid Catalyzed Chemodivergent Cycloadditions of Aryl Oxiranyldicarboxylates with Aldehydes, and Theoretical Rationalizations of Reaction Pathways // Chemistry - A European Journal. 2012. Vol. 18. No. 28. pp. 8591-8595.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201201453
UR - https://doi.org/10.1002/chem.201201453
TI - CO Versus CC Bond Cleavage: Selectivity Control in Lewis Acid Catalyzed Chemodivergent Cycloadditions of Aryl Oxiranyldicarboxylates with Aldehydes, and Theoretical Rationalizations of Reaction Pathways
T2 - Chemistry - A European Journal
AU - Chen, Zuliang
AU - Tian, Ziqi
AU - Zhang, Jieming
AU - Ma, Jing
AU - Zhang, Junliang
PY - 2012
DA - 2012/06/11
PB - Wiley
SP - 8591-8595
IS - 28
VL - 18
PMID - 22689542
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Chen,
author = {Zuliang Chen and Ziqi Tian and Jieming Zhang and Jing Ma and Junliang Zhang},
title = {CO Versus CC Bond Cleavage: Selectivity Control in Lewis Acid Catalyzed Chemodivergent Cycloadditions of Aryl Oxiranyldicarboxylates with Aldehydes, and Theoretical Rationalizations of Reaction Pathways},
journal = {Chemistry - A European Journal},
year = {2012},
volume = {18},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/chem.201201453},
number = {28},
pages = {8591--8595},
doi = {10.1002/chem.201201453}
}
Cite this
MLA
Copy
Chen, Zuliang, et al. “CO Versus CC Bond Cleavage: Selectivity Control in Lewis Acid Catalyzed Chemodivergent Cycloadditions of Aryl Oxiranyldicarboxylates with Aldehydes, and Theoretical Rationalizations of Reaction Pathways.” Chemistry - A European Journal, vol. 18, no. 28, Jun. 2012, pp. 8591-8595. https://doi.org/10.1002/chem.201201453.