Chemistry - A European Journal, volume 18, issue 44, pages 14017-14025

The First Catalytic Synthesis of an Acrylate from CO₂and an Alkene-A Rational Approach

Michael L Lejkowski ¹

Ronald Lindner ¹

Takeharu Kageyama ¹

Gabriella É Bódizs ¹

Philipp N. Plessow ^{1, 2}

Imke B. Müller ³

Ansgar Schäfer ³

Frank Rominger ⁴

Peter Hofmann ⁵

Cornelia Futter ⁶

Stephan A. Schunk ⁶

Michael Limbach ^{7, 8}

Hide authors affiliations Show authors affiliations: 8 affiliations

CaRLa (Catalysis Research Laboratory), Im Neuenheimer Feld 584, 69120 Heidelberg (Germany), Fax: (+49) 621-60-6648957 |

Quantum Chemistry, GVM/M-B009, BASF SE, Carl-Bosch-Strasse 38, 67056 Ludwigshafen (Germany) |

Quantum Chemistry, GVM/M‐B009, BASF SE, Carl‐Bosch‐Strasse 38, 67056 Ludwigshafen (Germany) |

⁴

Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany. |

⁵

Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg (Germany) |

⁶

hte Aktiengesellschaft, Kurpfalzring 104, 69123 Heidelberg (Germany) |

⁷

CaRLa (Catalysis Research Laboratory), Im Neuenheimer Feld 584, 69120 Heidelberg (Germany), Fax: (+49) 621‐60‐6648957 |

⁸

Synthesis and Homogeneous Catalysis, GCS/C‐M313, BASF SE, Carl‐Bosch‐Strasse 38, 67056 Ludwigshafen (Germany) |

Publication type: Journal Article

Publication date: 2012-09-20

Wiley

Journal: Chemistry - A European Journal

Quartile SCImago

Quartile WOS

Impact factor: 4.3

ISSN: 09476539, 15213765

DOI: 10.1002/chem.201201757

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General Chemistry

Catalysis

Organic Chemistry

Abstract

A dream come true: For over three decades the catalytic synthesis of acrylates from the cheap and abundantly available C1 building block CO2 and alkenes has been an unsolved problem in catalysis research. A homogeneous catalyst system based on a Ni complex has now been developed that permits the catalytic synthesis of Na acrylate from CO2, ethylene, and a base (see scheme), as shown by a turnover number of greater than 10 with respect to the metal.

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Lejkowski M. L. et al. The First Catalytic Synthesis of an Acrylate from CO2and an Alkene-A Rational Approach // Chemistry - A European Journal. 2012. Vol. 18. No. 44. pp. 14017-14025.

GOST all authors (up to 50) Copy

Lejkowski M. L., Lindner R., Kageyama T., Bódizs G. É., Plessow P. N., Müller I. B., Schäfer A., Rominger F., Hofmann P., Futter C., Schunk S. A., Limbach M. The First Catalytic Synthesis of an Acrylate from CO2and an Alkene-A Rational Approach // Chemistry - A European Journal. 2012. Vol. 18. No. 44. pp. 14017-14025.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/chem.201201757

UR - https://doi.org/10.1002/chem.201201757

TI - The First Catalytic Synthesis of an Acrylate from CO2and an Alkene-A Rational Approach

T2 - Chemistry - A European Journal

AU - Lejkowski, Michael L

AU - Lindner, Ronald

AU - Kageyama, Takeharu

AU - Bódizs, Gabriella É

AU - Plessow, Philipp N.

AU - Müller, Imke B.

AU - Schäfer, Ansgar

AU - Rominger, Frank

AU - Hofmann, Peter

AU - Futter, Cornelia

AU - Schunk, Stephan A.

AU - Limbach, Michael

PY - 2012

DA - 2012/09/20

PB - Wiley

SP - 14017-14025

IS - 44

VL - 18

SN - 0947-6539

SN - 1521-3765

ER -

BibTex |

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BibTex Copy

@article{2012_Lejkowski,

author = {Michael L Lejkowski and Ronald Lindner and Takeharu Kageyama and Gabriella É Bódizs and Philipp N. Plessow and Imke B. Müller and Ansgar Schäfer and Frank Rominger and Peter Hofmann and Cornelia Futter and Stephan A. Schunk and Michael Limbach},

title = {The First Catalytic Synthesis of an Acrylate from CO2and an Alkene-A Rational Approach},

journal = {Chemistry - A European Journal},

year = {2012},

volume = {18},

publisher = {Wiley},

month = {sep},

url = {https://doi.org/10.1002/chem.201201757},

number = {44},

pages = {14017--14025},

doi = {10.1002/chem.201201757}

}

MLA

Cite this

MLA Copy

Lejkowski, Michael L., et al. “The First Catalytic Synthesis of an Acrylate from CO2and an Alkene-A Rational Approach.” Chemistry - A European Journal, vol. 18, no. 44, Sep. 2012, pp. 14017-14025. https://doi.org/10.1002/chem.201201757.

Found error?

Publisher

Wiley

Journal

Chemistry - A European Journal

Quartile SCImago

Quartile WOS

Impact factor

4.3

ISSN

09476539 (Print)
15213765 (Electronic)