Luminescent metal-organic frameworks (MOFs) as a chemopalette: tuning the thermochromic behavior of dual-emissive phosphorescence by adjusting the supramolecular microenvironments.
Publication type: Journal Article
Publication date: 2013-06-18
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
23780783
General Chemistry
Catalysis
Organic Chemistry
Abstract
Two classical copper(I)-cluster-based luminophores, namely, Cu4I4 and [Cu3Pz3]2 (Pz = pyrazolate), are immobilized in a supramolecular system through the formation of metal-organic framework (MOF) materials. This series of luminescent MOF materials, namely, [Cu4I4(NH3)Cu3(L1)3]n, [Cu4I4(NH2CH3)Cu3(L1)3]n, and [Cu4I4Cu3(L2)3]n (L1 = 3-(4-pyridyl)-5-(p-tolyl)pyrazolate; L2 = 3-(4-pyridyl)-5-(2,4-dimethylphenyl)pyrazolate), exhibit diverse thermochromism attributed to the relative functioning efficacy of the two coordination luminophores. Such an intriguing chemopalette effect is regulated by the different supramolecular microenvironments between the two-dimensional layers of these MOFs, and in particular, by the fine-tuned Cu-Cu distances in the excimeric [Cu3Pz3]2 luminophore. The structure-property elucidation of the thermochromic behavior allows one to understand these optical materials with unusual dual-emissive properties.
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Zhan S. Z. et al. Luminescent metal-organic frameworks (MOFs) as a chemopalette: tuning the thermochromic behavior of dual-emissive phosphorescence by adjusting the supramolecular microenvironments. // Chemistry - A European Journal. 2013. Vol. 19. No. 31. pp. 10217-10225.
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Zhan S. Z., Li M., Ng S. W., Li D. Luminescent metal-organic frameworks (MOFs) as a chemopalette: tuning the thermochromic behavior of dual-emissive phosphorescence by adjusting the supramolecular microenvironments. // Chemistry - A European Journal. 2013. Vol. 19. No. 31. pp. 10217-10225.
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TY - JOUR
DO - 10.1002/chem.201204632
UR - https://doi.org/10.1002/chem.201204632
TI - Luminescent metal-organic frameworks (MOFs) as a chemopalette: tuning the thermochromic behavior of dual-emissive phosphorescence by adjusting the supramolecular microenvironments.
T2 - Chemistry - A European Journal
AU - Zhan, Shun Ze
AU - Li, Ming-De
AU - Ng, Seik Weng
AU - Li, Dan
PY - 2013
DA - 2013/06/18
PB - Wiley
SP - 10217-10225
IS - 31
VL - 19
PMID - 23780783
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2013_Zhan,
author = {Shun Ze Zhan and Ming-De Li and Seik Weng Ng and Dan Li},
title = {Luminescent metal-organic frameworks (MOFs) as a chemopalette: tuning the thermochromic behavior of dual-emissive phosphorescence by adjusting the supramolecular microenvironments.},
journal = {Chemistry - A European Journal},
year = {2013},
volume = {19},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/chem.201204632},
number = {31},
pages = {10217--10225},
doi = {10.1002/chem.201204632}
}
Cite this
MLA
Copy
Zhan, Shun Ze, et al. “Luminescent metal-organic frameworks (MOFs) as a chemopalette: tuning the thermochromic behavior of dual-emissive phosphorescence by adjusting the supramolecular microenvironments..” Chemistry - A European Journal, vol. 19, no. 31, Jun. 2013, pp. 10217-10225. https://doi.org/10.1002/chem.201204632.