Effect of Sodium Cation on Metallacycle β-Hydride Elimination in CO2-Ethylene Coupling to Acrylates
Тип публикации: Journal Article
Дата публикации: 2014-02-12
SCImago Q1
WOS Q2
БС1
SJR: 0.803
CiteScore: 5.8
Impact factor: 3.6
ISSN: 09476539, 15213765
PubMed ID:
24519890
General Chemistry
Catalysis
Organic Chemistry
Краткое описание
A sodium scramble: Sodium cations can be used to facilitate a β-hydride elimination reaction in CO2-derived nickelalactones, which is key to the production of acrylates. A related isomerization reaction can also occur without Lewis acid to produce rare unstabilized γ-nickelalactones, but with a higher activation energy and less favorable thermodynamics than the sodium-containing counterpart (see scheme).
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ГОСТ
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Dong J. et al. Effect of Sodium Cation on Metallacycle β-Hydride Elimination in CO2-Ethylene Coupling to Acrylates // Chemistry - A European Journal. 2014. Vol. 20. No. 11. pp. 3205-3211.
ГОСТ со всеми авторами (до 50)
Скопировать
Dong J., Williard P., Hazari N., Bernskoetter W. H. Effect of Sodium Cation on Metallacycle β-Hydride Elimination in CO2-Ethylene Coupling to Acrylates // Chemistry - A European Journal. 2014. Vol. 20. No. 11. pp. 3205-3211.
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RIS
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TY - JOUR
DO - 10.1002/chem.201304196
UR - https://doi.org/10.1002/chem.201304196
TI - Effect of Sodium Cation on Metallacycle β-Hydride Elimination in CO2-Ethylene Coupling to Acrylates
T2 - Chemistry - A European Journal
AU - Dong, Jin
AU - Williard, P.
AU - Hazari, Nilay
AU - Bernskoetter, Wesley H
PY - 2014
DA - 2014/02/12
PB - Wiley
SP - 3205-3211
IS - 11
VL - 20
PMID - 24519890
SN - 0947-6539
SN - 1521-3765
ER -
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BibTex (до 50 авторов)
Скопировать
@article{2014_Dong,
author = {Jin Dong and P. Williard and Nilay Hazari and Wesley H Bernskoetter},
title = {Effect of Sodium Cation on Metallacycle β-Hydride Elimination in CO2-Ethylene Coupling to Acrylates},
journal = {Chemistry - A European Journal},
year = {2014},
volume = {20},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/chem.201304196},
number = {11},
pages = {3205--3211},
doi = {10.1002/chem.201304196}
}
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MLA
Скопировать
Dong, Jin, et al. “Effect of Sodium Cation on Metallacycle β-Hydride Elimination in CO2-Ethylene Coupling to Acrylates.” Chemistry - A European Journal, vol. 20, no. 11, Feb. 2014, pp. 3205-3211. https://doi.org/10.1002/chem.201304196.
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