volume 20 issue 44 pages 14198-14200

Chlorination of Two Isomers of C86 Fullerene: Molecular Structures of C86(16)Cl16, C86(17)Cl18, C86(17)Cl20, and C86(17)Cl22

Publication typeJournal Article
Publication date2014-09-15
scimago Q1
wos Q2
SJR0.981
CiteScore6.7
Impact factor3.7
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract

Chlorination of a mixture of C86 isomers no. 16 (Cs) and no. 17 (C2) with VCl4 or a (TiCl4+Br2) mixture afforded crystalline chlorides with 16 to 22 Cl atoms per fullerene cage. Single crystal X‐ray diffraction with the use of synchrotron radiation enabled us to determine the chlorination patterns of C86(16)Cl16, C86(17)Cl18, C86(17)Cl20, and C86(17)Cl22. At these degrees of chlorination, addition patterns of C86(16) and C86(17) chlorides have some features in common, owing to the close similarity in the cage structures of both isomers. The average energy of CCl bonds decreases with increasing number of attached Cl atoms.

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Meng Xiangyue 孟., Wei T., Troyanov S. Chlorination of Two Isomers of C86 Fullerene: Molecular Structures of C86(16)Cl16, C86(17)Cl18, C86(17)Cl20, and C86(17)Cl22 // Chemistry - A European Journal. 2014. Vol. 20. No. 44. pp. 14198-14200.
GOST all authors (up to 50) Copy
Meng Xiangyue 孟., Wei T., Troyanov S. Chlorination of Two Isomers of C86 Fullerene: Molecular Structures of C86(16)Cl16, C86(17)Cl18, C86(17)Cl20, and C86(17)Cl22 // Chemistry - A European Journal. 2014. Vol. 20. No. 44. pp. 14198-14200.
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TY - JOUR
DO - 10.1002/chem.201404300
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201404300
TI - Chlorination of Two Isomers of C86 Fullerene: Molecular Structures of C86(16)Cl16, C86(17)Cl18, C86(17)Cl20, and C86(17)Cl22
T2 - Chemistry - A European Journal
AU - Meng Xiangyue, 孟祥月
AU - Wei, Tao
AU - Troyanov, Sergey
PY - 2014
DA - 2014/09/15
PB - Wiley
SP - 14198-14200
IS - 44
VL - 20
PMID - 25224824
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Meng Xiangyue,
author = {孟祥月 Meng Xiangyue and Tao Wei and Sergey Troyanov},
title = {Chlorination of Two Isomers of C86 Fullerene: Molecular Structures of C86(16)Cl16, C86(17)Cl18, C86(17)Cl20, and C86(17)Cl22},
journal = {Chemistry - A European Journal},
year = {2014},
volume = {20},
publisher = {Wiley},
month = {sep},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201404300},
number = {44},
pages = {14198--14200},
doi = {10.1002/chem.201404300}
}
MLA
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Meng Xiangyue, 孟祥月, et al. “Chlorination of Two Isomers of C86 Fullerene: Molecular Structures of C86(16)Cl16, C86(17)Cl18, C86(17)Cl20, and C86(17)Cl22.” Chemistry - A European Journal, vol. 20, no. 44, Sep. 2014, pp. 14198-14200. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201404300.