Chemistry - A European Journal, volume 20, issue 51, pages 16858-16862
Nickel-Catalyzed Direct Carboxylation of Olefins with CO2: One-Pot Synthesis of α,β-Unsaturated Carboxylic Acid Salts
Núria Huguet
1
,
Ivana Jevtovikj
1
,
Alvaro Gordillo
1
,
Michael L Lejkowski
1
,
Ronald Lindner
1
,
Miriam Bru
1
,
Andrey Y Khalimon
1
,
Frank Rominger
2
,
Stephan A. Schunk
3
,
Peter Hofmann
4
,
Michael Limbach
5, 6
1
CaRLa (Catalysis Research Laboratory), Im Neuenheimer Feld 584, 69120 Heidelberg (Germany), Fax: (+49) 621-60-6648957
|
3
hte GmbH, Kurpfalzring 104, 69123 Heidelberg (Germany)
|
5
BASF SE, Synthesis and Homogeneous Catalysis, Carl‐Bosch‐Strasse 38, 67056 Ludwigshafen (Germany)
|
6
CaRLa (Catalysis Research Laboratory), Im Neuenheimer Feld 584, 69120 Heidelberg (Germany), Fax: (+49) 621‐60‐6648957
|
Publication type: Journal Article
Publication date: 2014-10-30
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
The nickel-catalyzed direct carboxylation of alkenes with the cheap and abundantly available C1 building block carbon dioxide (CO2 ) in the presence of a base has been achieved. The one-pot reaction allows for the direct and selective synthesis of a wide range of α,β-unsaturated carboxylates (TON>100, TOF up to 6 h(-1) , TON=turnover number, TOF=turnover frequency). Thus, it is possible, in one step, to synthesize sodium acrylate from ethylene, CO2 , and a sodium salt. Acrylates are industrially important products, the synthesis of which has hitherto required multiple steps.
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GOST
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Huguet N. et al. Nickel-Catalyzed Direct Carboxylation of Olefins with CO2: One-Pot Synthesis of α,β-Unsaturated Carboxylic Acid Salts // Chemistry - A European Journal. 2014. Vol. 20. No. 51. pp. 16858-16862.
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Huguet N., Jevtovikj I., Gordillo A., Lejkowski M. L., Lindner R., Bru M., Khalimon A. Y., Rominger F., Schunk S. A., Hofmann P., Limbach M. Nickel-Catalyzed Direct Carboxylation of Olefins with CO2: One-Pot Synthesis of α,β-Unsaturated Carboxylic Acid Salts // Chemistry - A European Journal. 2014. Vol. 20. No. 51. pp. 16858-16862.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201405528
UR - https://doi.org/10.1002/chem.201405528
TI - Nickel-Catalyzed Direct Carboxylation of Olefins with CO2: One-Pot Synthesis of α,β-Unsaturated Carboxylic Acid Salts
T2 - Chemistry - A European Journal
AU - Huguet, Núria
AU - Jevtovikj, Ivana
AU - Gordillo, Alvaro
AU - Lejkowski, Michael L
AU - Lindner, Ronald
AU - Bru, Miriam
AU - Khalimon, Andrey Y
AU - Rominger, Frank
AU - Schunk, Stephan A.
AU - Hofmann, Peter
AU - Limbach, Michael
PY - 2014
DA - 2014/10/30
PB - Wiley
SP - 16858-16862
IS - 51
VL - 20
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex
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@article{2014_Huguet,
author = {Núria Huguet and Ivana Jevtovikj and Alvaro Gordillo and Michael L Lejkowski and Ronald Lindner and Miriam Bru and Andrey Y Khalimon and Frank Rominger and Stephan A. Schunk and Peter Hofmann and Michael Limbach},
title = {Nickel-Catalyzed Direct Carboxylation of Olefins with CO2: One-Pot Synthesis of α,β-Unsaturated Carboxylic Acid Salts},
journal = {Chemistry - A European Journal},
year = {2014},
volume = {20},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/chem.201405528},
number = {51},
pages = {16858--16862},
doi = {10.1002/chem.201405528}
}
Cite this
MLA
Copy
Huguet, Núria, et al. “Nickel-Catalyzed Direct Carboxylation of Olefins with CO2: One-Pot Synthesis of α,β-Unsaturated Carboxylic Acid Salts.” Chemistry - A European Journal, vol. 20, no. 51, Oct. 2014, pp. 16858-16862. https://doi.org/10.1002/chem.201405528.