volume 21 issue 11 pages 4242-4246

RhI-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed CC Bond Cleavages

Xu Fei Fu
Xiang Yu
Zhi-Xiang Yu
Publication typeJournal Article
Publication date2015-01-21
scimago Q1
wos Q2
SJR0.981
CiteScore6.7
Impact factor3.7
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
A Rh-catalyzed benzo/[7+1] cycloaddition of cyclopropyl-benzocyclobutenes (CP-BCBs) and CO to benzocyclooctenones has been developed. In this reaction, CP-BCB acts as a benzo/7-C synthon and the reaction involves two C-C bond cleavages: a thermal electrocyclic ring-opening of the four-membered ring in CP-BCB and a Rh-catalyzed C-C cleavage of the cyclopropane ring.
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GOST Copy
Fu X. F., Yu X., Yu Z. RhI-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed CC Bond Cleavages // Chemistry - A European Journal. 2015. Vol. 21. No. 11. pp. 4242-4246.
GOST all authors (up to 50) Copy
Fu X. F., Yu X., Yu Z. RhI-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed CC Bond Cleavages // Chemistry - A European Journal. 2015. Vol. 21. No. 11. pp. 4242-4246.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/chem.201405712
UR - https://doi.org/10.1002/chem.201405712
TI - RhI-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed CC Bond Cleavages
T2 - Chemistry - A European Journal
AU - Fu, Xu Fei
AU - Yu, Xiang
AU - Yu, Zhi-Xiang
PY - 2015
DA - 2015/01/21
PB - Wiley
SP - 4242-4246
IS - 11
VL - 21
PMID - 25612241
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Fu,
author = {Xu Fei Fu and Xiang Yu and Zhi-Xiang Yu},
title = {RhI-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed CC Bond Cleavages},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/chem.201405712},
number = {11},
pages = {4242--4246},
doi = {10.1002/chem.201405712}
}
MLA
Cite this
MLA Copy
Fu, Xu Fei, et al. “RhI-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed CC Bond Cleavages.” Chemistry - A European Journal, vol. 21, no. 11, Jan. 2015, pp. 4242-4246. https://doi.org/10.1002/chem.201405712.