Radical CH Alkylation of BODIPY Dyes Using Potassium Trifluoroborates or Boronic Acids
Bram Verbelen
1
,
L.C.D. Rezende
2, 3
,
Stijn Boodts
1
,
Jeroen Jacobs
1
,
Luc Van Meervelt
1
,
J. Hofkens
1
,
Publication type: Journal Article
Publication date: 2015-07-17
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
26215785
General Chemistry
Catalysis
Organic Chemistry
Abstract
A one-step synthetic procedure for the radical CH alkylation of BODIPY dyes has been developed. This new reaction generates alkyl radicals through the oxidation of boronic acids or potassium trifluoroborates and allows the synthesis of mono-, di-, tri-, and tetraalkylated fluorophores in a good to excellent yield for a broad range of organoboron compounds. Using this protocol, multiple bulky alkyl groups can be introduced onto the BODIPY core thus creating solid-state emissive BODIPY dyes.
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62
Total citations:
62
Citations from 2024:
10
(16.13%)
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MLA
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GOST
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Verbelen B. et al. Radical CH Alkylation of BODIPY Dyes Using Potassium Trifluoroborates or Boronic Acids // Chemistry - A European Journal. 2015. Vol. 21. No. 36. pp. 12667-12675.
GOST all authors (up to 50)
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Verbelen B., Rezende L., Boodts S., Jacobs J., Van Meervelt L., Hofkens J., Dehaen W. Radical CH Alkylation of BODIPY Dyes Using Potassium Trifluoroborates or Boronic Acids // Chemistry - A European Journal. 2015. Vol. 21. No. 36. pp. 12667-12675.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201500938
UR - https://doi.org/10.1002/chem.201500938
TI - Radical CH Alkylation of BODIPY Dyes Using Potassium Trifluoroborates or Boronic Acids
T2 - Chemistry - A European Journal
AU - Verbelen, Bram
AU - Rezende, L.C.D.
AU - Boodts, Stijn
AU - Jacobs, Jeroen
AU - Van Meervelt, Luc
AU - Hofkens, J.
AU - Dehaen, Wim
PY - 2015
DA - 2015/07/17
PB - Wiley
SP - 12667-12675
IS - 36
VL - 21
PMID - 26215785
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Verbelen,
author = {Bram Verbelen and L.C.D. Rezende and Stijn Boodts and Jeroen Jacobs and Luc Van Meervelt and J. Hofkens and Wim Dehaen},
title = {Radical CH Alkylation of BODIPY Dyes Using Potassium Trifluoroborates or Boronic Acids},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/chem.201500938},
number = {36},
pages = {12667--12675},
doi = {10.1002/chem.201500938}
}
Cite this
MLA
Copy
Verbelen, Bram, et al. “Radical CH Alkylation of BODIPY Dyes Using Potassium Trifluoroborates or Boronic Acids.” Chemistry - A European Journal, vol. 21, no. 36, Jul. 2015, pp. 12667-12675. https://doi.org/10.1002/chem.201500938.