Chemistry - A European Journal, volume 21, issue 49, pages 17921-17932
Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates
Kalyakina Alena S
1, 2
,
Utochnikova Valentina
3, 4
,
Ananyev Ivan V
5
,
Eremenko Igor L.
6
,
Volz Daniel
2, 7
,
Rönicke Franziska
8
,
Schepers U.
8
,
Deun Rik Van
9
,
Trigub Alexander L.
10
,
Zubavichus Yan V.
10
,
Kuzmina Natalia P.
11
,
Bräse Stefan
12
7
Cynora GmbH, Werner-von-Siemens-Straße 2-6, 76646 Bruchsal (Germany)
|
Publication type: Journal Article
Publication date: 2015-10-22
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
Highly luminescent, photostable, and soluble lanthanide pentafluorobenzoates have been synthesized and thoroughly characterized, with a focus on Eu(III) and Tb(III) complexes as visible emitters and Nd(III) , Er(III) , and Yb(III) complexes as infrared emitters. Investigation of the crystal structures of the complexes in powder form and as single crystals by using X-ray diffraction revealed five different structural types, including monomeric, dimeric, and polymeric. The local structure in different solutions was studied by using X-ray absorption spectroscopy. The photoluminescence quantum yields (PLQYs) of terbium and europium complexes were 39 and 15 %, respectively; the latter value was increased almost twice by using the heterometallic complex [Tb0.5 Eu0.5 (pfb)3 (H2 O)] (Hpfb=pentafluorobenzoic acid). Due to the effectively utilized sensitization strategy (pfb)(-) →Tb→Eu, a pure europium luminescence with a PLQY of 29 % was achieved.
Citations by journals
1
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3
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5
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2 publications, 3.45%
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2 publications, 3.45%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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Chemistry - A European Journal
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1 publication, 1.72%
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1
2
3
4
5
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Citations by publishers
5
10
15
20
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Elsevier
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20 publications, 34.48%
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9 publications, 15.52%
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8 publications, 13.79%
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Wiley
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6 publications, 10.34%
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4 publications, 6.9%
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Walter de Gruyter
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2 publications, 3.45%
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Springer Nature
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Springer Nature
2 publications, 3.45%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
2 publications, 3.45%
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IOP Publishing
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IOP Publishing
1 publication, 1.72%
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CSIRO Publishing
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CSIRO Publishing
1 publication, 1.72%
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American Institute of Physics (AIP)
|
American Institute of Physics (AIP)
1 publication, 1.72%
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Chinese Society of Rare Earths
|
Chinese Society of Rare Earths
1 publication, 1.72%
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Trans Tech Publications
|
Trans Tech Publications
1 publication, 1.72%
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5
10
15
20
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kalyakina A. S. et al. Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates // Chemistry - A European Journal. 2015. Vol. 21. No. 49. pp. 17921-17932.
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Kalyakina A. S., Utochnikova V., Bushmarinov I. S., Ananyev I. V., Eremenko I. L., Volz D., Rönicke F., Schepers U., Deun R. V., Trigub A. L., Zubavichus Y. V., Kuzmina N. P., Bräse S. Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates // Chemistry - A European Journal. 2015. Vol. 21. No. 49. pp. 17921-17932.
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TY - JOUR
DO - 10.1002/chem.201501816
UR - https://doi.org/10.1002%2Fchem.201501816
TI - Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates
T2 - Chemistry - A European Journal
AU - Volz, Daniel
AU - Rönicke, Franziska
AU - Kalyakina, Alena S
AU - Utochnikova, Valentina
AU - Bushmarinov, I. S.
AU - Ananyev, Ivan V
AU - Eremenko, Igor L.
AU - Schepers, U.
AU - Deun, Rik Van
AU - Trigub, Alexander L.
AU - Zubavichus, Yan V.
AU - Kuzmina, Natalia P.
AU - Bräse, Stefan
PY - 2015
DA - 2015/10/22 00:00:00
PB - Wiley
SP - 17921-17932
IS - 49
VL - 21
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2015_Kalyakina,
author = {Daniel Volz and Franziska Rönicke and Alena S Kalyakina and Valentina Utochnikova and I. S. Bushmarinov and Ivan V Ananyev and Igor L. Eremenko and U. Schepers and Rik Van Deun and Alexander L. Trigub and Yan V. Zubavichus and Natalia P. Kuzmina and Stefan Bräse},
title = {Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002%2Fchem.201501816},
number = {49},
pages = {17921--17932},
doi = {10.1002/chem.201501816}
}
Cite this
MLA
Copy
Kalyakina, Alena S., et al. “Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates.” Chemistry - A European Journal, vol. 21, no. 49, Oct. 2015, pp. 17921-17932. https://doi.org/10.1002%2Fchem.201501816.