Chemistry - A European Journal, volume 21, issue 49, pages 17921-17932

Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates

Kalyakina Alena S ^{1, 2}

Utochnikova Valentina ^{3, 4}

Bushmarinov I. S. ⁵

Ananyev Ivan V ⁵

Eremenko Igor L. ⁶

Volz Daniel ^{2, 7}

Rönicke Franziska ⁸

Schepers U. ⁸

Deun Rik Van ⁹

Trigub Alexander L. ¹⁰

Zubavichus Yan V. ¹⁰

Kuzmina Natalia P. ¹¹

Bräse Stefan ¹²

Hide authors affiliations Show authors affiliations: 12 affiliations

Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, 1, build.3, 119991, Moscow (Russian Federation) |

Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz‐Haber‐Weg 6, D‐76131 Karlsruhe (Germany) |

Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, 1, Build.3, 119991, Moscow, Russian Federation |

⁴

P. N. Lebedev Physical Institute Leninsky prosp. 53 119991 Moscow Russian Federation |

⁵

A. N. Nesmeyanov Institute of Organoelement Compounds, Vavilova St. 28, INEOS, 119991, Moscow, Russian Federation. |

⁶

Kurnakov Institute of General and Inorganic Chemistry, Leninsky prosp. 31, 119991, Moscow (Russian Federation) |

⁷

Cynora GmbH, Werner-von-Siemens-Straße 2-6, 76646 Bruchsal (Germany) |

⁸

Institute of Toxicology and Genetics, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen (Germany). |

⁹

L3‐Luminescent Lanthanide Lab, f‐Element Coordination Chemistry, Inorganic and Physical Chemistry Department, Ghent University, Krijgslaan 281, building S3, 9000 Gent (Belgium) |

¹⁰

NRC Kurchatov Institute, Akademika Kurchatova pl. 1, 123182, Moscow (Russian Federation). |

¹¹

Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, 1, build.3, 119991 Moscow, Russian Federation |

¹²

Institute of Toxicology and Genetics, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen (Germany) |

Publication type: Journal Article

Publication date: 2015-10-22

Wiley

Journal: Chemistry - A European Journal

Quartile SCImago

Quartile WOS

Impact factor: 4.3

ISSN: 09476539, 15213765

DOI: 10.1002/chem.201501816

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General Chemistry

Catalysis

Organic Chemistry

Abstract

Highly luminescent, photostable, and soluble lanthanide pentafluorobenzoates have been synthesized and thoroughly characterized, with a focus on Eu(III) and Tb(III) complexes as visible emitters and Nd(III) , Er(III) , and Yb(III) complexes as infrared emitters. Investigation of the crystal structures of the complexes in powder form and as single crystals by using X-ray diffraction revealed five different structural types, including monomeric, dimeric, and polymeric. The local structure in different solutions was studied by using X-ray absorption spectroscopy. The photoluminescence quantum yields (PLQYs) of terbium and europium complexes were 39 and 15 %, respectively; the latter value was increased almost twice by using the heterometallic complex [Tb0.5 Eu0.5 (pfb)3 (H2 O)] (Hpfb=pentafluorobenzoic acid). Due to the effectively utilized sensitization strategy (pfb)(-) →Tb→Eu, a pure europium luminescence with a PLQY of 29 % was achieved.

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Citations by journals

	1 2 3 4 5
European Journal of Inorganic Chemistry	European Journal of Inorganic Chemistry, 5, 8.62% European Journal of Inorganic Chemistry 5 publications, 8.62%
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 5, 8.62% Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya 5 publications, 8.62%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 3, 5.17% Coordination Chemistry Reviews 3 publications, 5.17%
Dalton Transactions	Dalton Transactions, 3, 5.17% Dalton Transactions 3 publications, 5.17%
Journal of Molecular Structure	Journal of Molecular Structure, 3, 5.17% Journal of Molecular Structure 3 publications, 5.17%
Optical Materials	Optical Materials, 2, 3.45% Optical Materials 2 publications, 3.45%
New Journal of Chemistry	New Journal of Chemistry, 2, 3.45% New Journal of Chemistry 2 publications, 3.45%
Journal of Luminescence	Journal of Luminescence, 2, 3.45% Journal of Luminescence 2 publications, 3.45%
Dyes and Pigments	Dyes and Pigments, 2, 3.45% Dyes and Pigments 2 publications, 3.45%
Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 2, 3.45% Russian Journal of Inorganic Chemistry 2 publications, 3.45%
Handbook on the Physics and Chemistry of Rare Earths	Handbook on the Physics and Chemistry of Rare Earths, 2, 3.45% Handbook on the Physics and Chemistry of Rare Earths 2 publications, 3.45%
Inorganics	Inorganics, 2, 3.45% Inorganics 2 publications, 3.45%
Polyhedron	Polyhedron, 2, 3.45% Polyhedron 2 publications, 3.45%
Pure and Applied Chemistry	Pure and Applied Chemistry, 1, 1.72% Pure and Applied Chemistry 1 publication, 1.72%
Russian Chemical Bulletin	Russian Chemical Bulletin, 1, 1.72% Russian Chemical Bulletin 1 publication, 1.72%
Materials	Materials, 1, 1.72% Materials 1 publication, 1.72%
Chemistry - A European Journal	Chemistry - A European Journal, 1, 1.72% Chemistry - A European Journal 1 publication, 1.72%
Organic Electronics	Organic Electronics, 1, 1.72% Organic Electronics 1 publication, 1.72%
Chemical Communications	Chemical Communications, 1, 1.72% Chemical Communications 1 publication, 1.72%
Molecules	Molecules, 1, 1.72% Molecules 1 publication, 1.72%
Chemistry of Materials	Chemistry of Materials, 1, 1.72% Chemistry of Materials 1 publication, 1.72%
Journal of Physics: Conference Series	Journal of Physics: Conference Series, 1, 1.72% Journal of Physics: Conference Series 1 publication, 1.72%
Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 1, 1.72% Physical Chemistry Chemical Physics 1 publication, 1.72%
Australian Journal of Chemistry	Australian Journal of Chemistry, 1, 1.72% Australian Journal of Chemistry 1 publication, 1.72%
The Analyst	The Analyst, 1, 1.72% The Analyst 1 publication, 1.72%
Applied Physics Letters	Applied Physics Letters, 1, 1.72% Applied Physics Letters 1 publication, 1.72%
Journal of Rare Earths	Journal of Rare Earths, 1, 1.72% Journal of Rare Earths 1 publication, 1.72%
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 1, 1.72% Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 1 publication, 1.72%
Inorganica Chimica Acta	Inorganica Chimica Acta, 1, 1.72% Inorganica Chimica Acta 1 publication, 1.72%
Inorganic Chemistry Communication	Inorganic Chemistry Communication, 1, 1.72% Inorganic Chemistry Communication 1 publication, 1.72%
	1 2 3 4 5

Citations by publishers

	5 10 15 20
Elsevier	Elsevier, 20, 34.48% Elsevier 20 publications, 34.48%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 9, 15.52% Royal Society of Chemistry (RSC) 9 publications, 15.52%
Pleiades Publishing	Pleiades Publishing, 8, 13.79% Pleiades Publishing 8 publications, 13.79%
Wiley	Wiley, 6, 10.34% Wiley 6 publications, 10.34%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 4, 6.9% Multidisciplinary Digital Publishing Institute (MDPI) 4 publications, 6.9%
Walter de Gruyter	Walter de Gruyter, 2, 3.45% Walter de Gruyter 2 publications, 3.45%
Springer Nature	Springer Nature, 2, 3.45% Springer Nature 2 publications, 3.45%
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 3.45% American Chemical Society (ACS) 2 publications, 3.45%
IOP Publishing	IOP Publishing, 1, 1.72% IOP Publishing 1 publication, 1.72%
CSIRO Publishing	CSIRO Publishing, 1, 1.72% CSIRO Publishing 1 publication, 1.72%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 1.72% American Institute of Physics (AIP) 1 publication, 1.72%
Chinese Society of Rare Earths	Chinese Society of Rare Earths, 1, 1.72% Chinese Society of Rare Earths 1 publication, 1.72%
Trans Tech Publications	Trans Tech Publications, 1, 1.72% Trans Tech Publications 1 publication, 1.72%
	5 10 15 20

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Kalyakina A. S. et al. Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates // Chemistry - A European Journal. 2015. Vol. 21. No. 49. pp. 17921-17932.

GOST all authors (up to 50) Copy

Kalyakina A. S., Utochnikova V., Bushmarinov I. S., Ananyev I. V., Eremenko I. L., Volz D., Rönicke F., Schepers U., Deun R. V., Trigub A. L., Zubavichus Y. V., Kuzmina N. P., Bräse S. Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates // Chemistry - A European Journal. 2015. Vol. 21. No. 49. pp. 17921-17932.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/chem.201501816

UR - https://doi.org/10.1002%2Fchem.201501816

TI - Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates

T2 - Chemistry - A European Journal

AU - Volz, Daniel

AU - Rönicke, Franziska

AU - Kalyakina, Alena S

AU - Utochnikova, Valentina

AU - Bushmarinov, I. S.

AU - Ananyev, Ivan V

AU - Eremenko, Igor L.

AU - Schepers, U.

AU - Deun, Rik Van

AU - Trigub, Alexander L.

AU - Zubavichus, Yan V.

AU - Kuzmina, Natalia P.

AU - Bräse, Stefan

PY - 2015

DA - 2015/10/22 00:00:00

PB - Wiley

SP - 17921-17932

IS - 49

VL - 21

SN - 0947-6539

SN - 1521-3765

ER -

BibTex |

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BibTex Copy

@article{2015_Kalyakina,

author = {Daniel Volz and Franziska Rönicke and Alena S Kalyakina and Valentina Utochnikova and I. S. Bushmarinov and Ivan V Ananyev and Igor L. Eremenko and U. Schepers and Rik Van Deun and Alexander L. Trigub and Yan V. Zubavichus and Natalia P. Kuzmina and Stefan Bräse},

title = {Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates},

journal = {Chemistry - A European Journal},

year = {2015},

volume = {21},

publisher = {Wiley},

month = {oct},

url = {https://doi.org/10.1002%2Fchem.201501816},

number = {49},

pages = {17921--17932},

doi = {10.1002/chem.201501816}

}

MLA

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MLA Copy

Kalyakina, Alena S., et al. “Highly Luminescent, Water-Soluble Lanthanide Fluorobenzoates: Syntheses, Structures and Photophysics, Part I: Lanthanide Pentafluorobenzoates.” Chemistry - A European Journal, vol. 21, no. 49, Oct. 2015, pp. 17921-17932. https://doi.org/10.1002%2Fchem.201501816.

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Publisher

Wiley

Journal

Chemistry - A European Journal

Quartile SCImago

Quartile WOS

Impact factor

4.3

ISSN

09476539 (Print)
15213765 (Electronic)

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