Chemistry - A European Journal, volume 21, issue 37, pages 12903-12907
Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation
Publication type: Journal Article
Publication date: 2015-07-28
Journal:
Chemistry - A European Journal
Q1
Q2
SJR: 1.058
CiteScore: 7.9
Impact factor: 3.9
ISSN: 09476539, 15213765
PubMed ID:
26235369
General Chemistry
Catalysis
Organic Chemistry
Abstract
The first examples of diastereo- and enantioselective carbonyl α-(cyclopropyl)allylation are reported. Under the conditions of iridium catalyzed transfer hydrogenation using the chiral precatalyst (R)-Ir-I modified by SEGPHOS, carbonyl α-(cyclopropyl)allylation may be achieved with equal facility from alcohol or aldehyde oxidation levels. This methodology provides a conduit to hitherto inaccessible inaccessible enantiomerically enriched cyclopropane-containing architectures.
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Tsutsumi R., Hong S., Krische M. J. Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation // Chemistry - A European Journal. 2015. Vol. 21. No. 37. pp. 12903-12907.
GOST all authors (up to 50)
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Tsutsumi R., Hong S., Krische M. J. Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation // Chemistry - A European Journal. 2015. Vol. 21. No. 37. pp. 12903-12907.
Cite this
RIS
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TY - JOUR
DO - 10.1002/chem.201502499
UR - https://doi.org/10.1002/chem.201502499
TI - Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation
T2 - Chemistry - A European Journal
AU - Tsutsumi, R.
AU - Hong, Suckchang
AU - Krische, Michael J
PY - 2015
DA - 2015/07/28
PB - Wiley
SP - 12903-12907
IS - 37
VL - 21
PMID - 26235369
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Tsutsumi,
author = {R. Tsutsumi and Suckchang Hong and Michael J Krische},
title = {Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/chem.201502499},
number = {37},
pages = {12903--12907},
doi = {10.1002/chem.201502499}
}
Cite this
MLA
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Tsutsumi, R., et al. “Diastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation.” Chemistry - A European Journal, vol. 21, no. 37, Jul. 2015, pp. 12903-12907. https://doi.org/10.1002/chem.201502499.