Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates
Publication type: Journal Article
Publication date: 2016-06-17
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
27311877
General Chemistry
Catalysis
Organic Chemistry
Abstract
Hydrogenation and transfer hydrogenation of imines with cyclohexa-1,4-dienes, as well as with a representative Hantzsch ester dihydrogen surrogate, are reported. Both processes are catalyzed by tethered Ru-S complexes but differ in the activation mode of the dihydrogen source: cooperative activation of the H-H bond at the Ru-S bond leads to the corresponding Ru-H complex and protonation of the sulfur atom, whereas the same cationic Ru-S catalyst abstracts a hydride from a donor-substituted cyclohexa-1,4-diene to form the neutral Ru-H complex and a low-energy Wheland intermediate. A sequence of proton and hydride transfers on the imine substrate then yields an amine. The reaction pathways are analyzed computationally, and the established mechanistic pictures are in agreement with the experimental observations.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
|
|
|
Chemistry - A European Journal
4 publications, 9.52%
|
|
|
Organometallics
4 publications, 9.52%
|
|
|
Angewandte Chemie - International Edition
2 publications, 4.76%
|
|
|
Angewandte Chemie
2 publications, 4.76%
|
|
|
Journal of the American Chemical Society
2 publications, 4.76%
|
|
|
ACS Catalysis
2 publications, 4.76%
|
|
|
Inorganic Chemistry
2 publications, 4.76%
|
|
|
Chemical Science
2 publications, 4.76%
|
|
|
RSC Advances
2 publications, 4.76%
|
|
|
Organic Reaction Mechanisms
2 publications, 4.76%
|
|
|
Synlett
2 publications, 4.76%
|
|
|
European Journal of Organic Chemistry
1 publication, 2.38%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 2.38%
|
|
|
Organic Letters
1 publication, 2.38%
|
|
|
Accounts of Chemical Research
1 publication, 2.38%
|
|
|
ACS Omega
1 publication, 2.38%
|
|
|
Journal of Organic Chemistry
1 publication, 2.38%
|
|
|
Comments on Inorganic Chemistry
1 publication, 2.38%
|
|
|
ChemistryOpen
1 publication, 2.38%
|
|
|
Russian Chemical Reviews
1 publication, 2.38%
|
|
|
ChemistryEurope
1 publication, 2.38%
|
|
|
ChemSusChem
1 publication, 2.38%
|
|
|
ChemCatChem
1 publication, 2.38%
|
|
|
1
2
3
4
|
Publishers
|
2
4
6
8
10
12
14
16
18
|
|
|
Wiley
17 publications, 40.48%
|
|
|
American Chemical Society (ACS)
14 publications, 33.33%
|
|
|
Royal Society of Chemistry (RSC)
4 publications, 9.52%
|
|
|
Elsevier
3 publications, 7.14%
|
|
|
Georg Thieme Verlag KG
2 publications, 4.76%
|
|
|
Taylor & Francis
1 publication, 2.38%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.38%
|
|
|
2
4
6
8
10
12
14
16
18
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
42
Total citations:
42
Citations from 2024:
9
(21.42%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Lefranc A. et al. Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates // Chemistry - A European Journal. 2016. Vol. 22. No. 29. pp. 10009-10016.
GOST all authors (up to 50)
Copy
Lefranc A., Qu Z., Grimme S., Oestreich M. Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates // Chemistry - A European Journal. 2016. Vol. 22. No. 29. pp. 10009-10016.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201600386
UR - https://doi.org/10.1002/chem.201600386
TI - Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates
T2 - Chemistry - A European Journal
AU - Lefranc, Alice
AU - Qu, Zheng-Wang
AU - Grimme, Stefan
AU - Oestreich, Martin
PY - 2016
DA - 2016/06/17
PB - Wiley
SP - 10009-10016
IS - 29
VL - 22
PMID - 27311877
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Lefranc,
author = {Alice Lefranc and Zheng-Wang Qu and Stefan Grimme and Martin Oestreich},
title = {Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates},
journal = {Chemistry - A European Journal},
year = {2016},
volume = {22},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/chem.201600386},
number = {29},
pages = {10009--10016},
doi = {10.1002/chem.201600386}
}
Cite this
MLA
Copy
Lefranc, Alice, et al. “Hydrogenation and Transfer Hydrogenation Promoted by Tethered Ru−S Complexes: From Cooperative Dihydrogen Activation to Hydride Abstraction/Proton Release from Dihydrogen Surrogates.” Chemistry - A European Journal, vol. 22, no. 29, Jun. 2016, pp. 10009-10016. https://doi.org/10.1002/chem.201600386.