Formation of a peri ‐Bridged Phosphonio‐Naphthalene by Cu‐Mediated Phosphine–Aryl Coupling
Тип публикации: Journal Article
Дата публикации: 2018-06-25
scimago Q1
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SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
29846985
General Chemistry
Catalysis
Organic Chemistry
Краткое описание
The peri-iodo naphthyl phosphine 1 reacts with CuI to give the peri-bridged phosphonio-naphthalene 2, which has been fully characterized (multi-nuclear NMR, MS, XRD). The outcome of the reaction differs markedly from that observed with gold. A two-step pathway involving P-assisted C-I oxidative addition to copper, followed by P-C reductive elimination is shown to be energetically feasible by DFT calculations.
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Blons C. et al. Formation of a peri ‐Bridged Phosphonio‐Naphthalene by Cu‐Mediated Phosphine–Aryl Coupling // Chemistry - A European Journal. 2018. Vol. 24. No. 46. pp. 11922-11925.
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Blons C., Duval M., Delcroix D., Olivier-Bourbigou H., Mallet-Ladeira S., Sosa Carrizo E. D., Miqueu K., Amgoune A., Bourissou D. Formation of a peri ‐Bridged Phosphonio‐Naphthalene by Cu‐Mediated Phosphine–Aryl Coupling // Chemistry - A European Journal. 2018. Vol. 24. No. 46. pp. 11922-11925.
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TY - JOUR
DO - 10.1002/chem.201802579
UR - https://doi.org/10.1002/chem.201802579
TI - Formation of a peri ‐Bridged Phosphonio‐Naphthalene by Cu‐Mediated Phosphine–Aryl Coupling
T2 - Chemistry - A European Journal
AU - Blons, Charlie
AU - Duval, Maryne
AU - Delcroix, D
AU - Olivier-Bourbigou, Hélène
AU - Mallet-Ladeira, Sonia
AU - Sosa Carrizo, E Daiann
AU - Miqueu, Karinne
AU - Amgoune, Abderrahmane
AU - Bourissou, Didier
PY - 2018
DA - 2018/06/25
PB - Wiley
SP - 11922-11925
IS - 46
VL - 24
PMID - 29846985
SN - 0947-6539
SN - 1521-3765
ER -
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BibTex (до 50 авторов)
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@article{2018_Blons,
author = {Charlie Blons and Maryne Duval and D Delcroix and Hélène Olivier-Bourbigou and Sonia Mallet-Ladeira and E Daiann Sosa Carrizo and Karinne Miqueu and Abderrahmane Amgoune and Didier Bourissou},
title = {Formation of a peri ‐Bridged Phosphonio‐Naphthalene by Cu‐Mediated Phosphine–Aryl Coupling},
journal = {Chemistry - A European Journal},
year = {2018},
volume = {24},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/chem.201802579},
number = {46},
pages = {11922--11925},
doi = {10.1002/chem.201802579}
}
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MLA
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Blons, Charlie, et al. “Formation of a peri ‐Bridged Phosphonio‐Naphthalene by Cu‐Mediated Phosphine–Aryl Coupling.” Chemistry - A European Journal, vol. 24, no. 46, Jun. 2018, pp. 11922-11925. https://doi.org/10.1002/chem.201802579.