Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding
Тип публикации: Journal Article
Дата публикации: 2019-08-28
scimago Q1
wos Q2
БС1
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
31232494
General Chemistry
Catalysis
Organic Chemistry
Краткое описание
The isocyanide trans‐[PdBr2(CNC6H4‐4‐X′)2] (X′=Br, I) and nitrile trans‐[PtX2(NCC6H4‐4‐X′)2] (X/X′=Cl/Cl, Cl/Br, Br/Cl, Br/Br) complexes exhibit similar structural motif in the solid state, which is determined by hitherto unreported four‐center nodes formed by cyclic halogen bonding. Each node is built up by four Type II C−X′⋅⋅⋅X−M halogen‐bonding contacts and include one Type I M−X⋅⋅⋅X−M interaction, thus giving the rhombic‐like structure. These nodes serve as supramolecular synthons to form 2D layers or double chains of molecules linked by a halogen bond. Results of DFT calculations indicate that all contacts within the nodes are typical noncovalent interactions with the estimated strengths in the range 0.6–2.9 kcal mol−1.
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Kryukova M. A. et al. Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding // Chemistry - A European Journal. 2019. Vol. 25. No. 60. pp. 13671-13675.
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Kryukova M. A., Ivanov D. M., Kinzhalov M. A., Novikov A. S., Smirnov M. S., Bokach N. A., Kukushkin V. Y. Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding // Chemistry - A European Journal. 2019. Vol. 25. No. 60. pp. 13671-13675.
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TY - JOUR
DO - 10.1002/chem.201902264
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201902264
TI - Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding
T2 - Chemistry - A European Journal
AU - Kryukova, Mariya A
AU - Ivanov, Daniil M
AU - Kinzhalov, M. A.
AU - Novikov, Alexander S.
AU - Smirnov, Mikhail S.
AU - Bokach, Nadezhda A.
AU - Kukushkin, Vadim Yu.
PY - 2019
DA - 2019/08/28
PB - Wiley
SP - 13671-13675
IS - 60
VL - 25
PMID - 31232494
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2019_Kryukova,
author = {Mariya A Kryukova and Daniil M Ivanov and M. A. Kinzhalov and Alexander S. Novikov and Mikhail S. Smirnov and Nadezhda A. Bokach and Vadim Yu. Kukushkin},
title = {Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding},
journal = {Chemistry - A European Journal},
year = {2019},
volume = {25},
publisher = {Wiley},
month = {aug},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201902264},
number = {60},
pages = {13671--13675},
doi = {10.1002/chem.201902264}
}
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MLA
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Kryukova, Mariya A., et al. “Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding.” Chemistry - A European Journal, vol. 25, no. 60, Aug. 2019, pp. 13671-13675. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201902264.
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