volume 26 issue 72 pages 17386-17389

Completing the Redox‐Series of Silicon Trisdioxolene: ortho ‐Quinone and Lewis Superacid Make a Powerful Redox Catalyst

Publication typeJournal Article
Publication date2020-11-24
scimago Q1
wos Q2
SJR0.981
CiteScore6.7
Impact factor3.7
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
Series finale: The redox chemistry of silicon tris(perchlorodioxolene) is studied and the series completed by the isolation of the monoradical anion. The neutral diradical state turns out to be a remarkably potent oxidant (as strong as “magic blue” or NO+) and redox catalyst, which can be generated from SiI4 and ortho-chloranil in situ. In a more general sense, this study serves as a blueprint for the redox-amplification of ortho-quinones by Lewis acid binding.
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GOST Copy
Maskey R. et al. Completing the Redox‐Series of Silicon Trisdioxolene: ortho ‐Quinone and Lewis Superacid Make a Powerful Redox Catalyst // Chemistry - A European Journal. 2020. Vol. 26. No. 72. pp. 17386-17389.
GOST all authors (up to 50) Copy
Maskey R., Bendel C., Malzacher J., Greb L. Completing the Redox‐Series of Silicon Trisdioxolene: ortho ‐Quinone and Lewis Superacid Make a Powerful Redox Catalyst // Chemistry - A European Journal. 2020. Vol. 26. No. 72. pp. 17386-17389.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/chem.202004712
UR - https://doi.org/10.1002/chem.202004712
TI - Completing the Redox‐Series of Silicon Trisdioxolene: ortho ‐Quinone and Lewis Superacid Make a Powerful Redox Catalyst
T2 - Chemistry - A European Journal
AU - Maskey, Rezisha
AU - Bendel, Christoph
AU - Malzacher, Jonas
AU - Greb, L
PY - 2020
DA - 2020/11/24
PB - Wiley
SP - 17386-17389
IS - 72
VL - 26
PMID - 33108014
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Maskey,
author = {Rezisha Maskey and Christoph Bendel and Jonas Malzacher and L Greb},
title = {Completing the Redox‐Series of Silicon Trisdioxolene: ortho ‐Quinone and Lewis Superacid Make a Powerful Redox Catalyst},
journal = {Chemistry - A European Journal},
year = {2020},
volume = {26},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/chem.202004712},
number = {72},
pages = {17386--17389},
doi = {10.1002/chem.202004712}
}
MLA
Cite this
MLA Copy
Maskey, Rezisha, et al. “Completing the Redox‐Series of Silicon Trisdioxolene: ortho ‐Quinone and Lewis Superacid Make a Powerful Redox Catalyst.” Chemistry - A European Journal, vol. 26, no. 72, Nov. 2020, pp. 17386-17389. https://doi.org/10.1002/chem.202004712.