Chemistry - A European Journal

, volume 29 , issue 44 , publication number e202300948

First Example of 1,2,5‐Oxadiazole‐Based Hypergolic Ionic Liquids: a New Class of Potential Energetic Fuels

Alexander V Shaferov ¹

Sergey T. Arakelov ^{1, 2}

Fedor E Teslenko ¹

Alla N Pivkina ³

Nikita V Muravyev ³

Leonid L. Fershtat ^{1, 2}

Hide authors affiliations Show authors affiliations: 3 affiliations

N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences 119991 Leninsky Prospect, 47 Moscow Russia |

National Research University Higher School of Economics 101000 Myasnitskaya str., 20 Moscow Russia |

N. N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences 119991 Kosygin str., 4 Moscow Russia |

Publication type: Journal Article

Publication date: 2023-07-06

Wiley

Chemistry - A European Journal

scimago Q1

wos Q2

SJR: 0.981

CiteScore: 6.7

Impact factor: 3.7

ISSN: 09476539, 15213765

DOI: 10.1002/chem.202300948

Copy DOI

PubMed ID: 37216337

General Chemistry

Catalysis

Organic Chemistry

Abstract

The development of liquid energetic fuels with improved properties is an important topic in space propulsion technologies. In this manuscript, a series of energetic ionic liquids incorporating a 1,2,5‐oxadiazole ring and nitrate, dicyanamide or dinitramide anion was synthesized and their physicochemical properties were evaluated. The synthesized compounds were fully characterized and were found to have good thermal stabilities (up to 219 °C) and experimental densities (1.21–1.47 g cm⁻³). Advantageously, 1,2,5‐oxadiazole‐based ionic liquids have high combined nitrogen‐oxygen contents (up to 64.4 %), while their detonation velocities are on the level of known explosive TNT, and combustion performance exceeds those of benchmark 2‐hydroxyethylhydrazinium nitrate. Considering the established hypergolicity with H₂O₂ in the presence of a catalyst, and insensitivity to impact, synthesized ionic liquids have strong application potential as energetic fuels for space technologies.

Found

9 citations

Fershtat Leonid

DSc in Chemistry

146 publications, 2 980 citations, 121 reviews

h-index: 29

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

4 citations

Larin Alexander

PhD in Chemistry

44 publications, 751 citations, 16 reviews

h-index: 16

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Pharmaceutical Chemistry

3 citations

Vinogradov Dmitry

PhD in Chemistry

10 publications, 48 citations

h-index: 4

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Organic Chemistry

2 citations

Ananyev Ivan

DSc in Physics and Mathematics

167 publications, 2 854 citations, 19 reviews

h-index: 30

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

National Research University Higher School of Economics

2 citations

Shaferov Alexander

12 publications, 192 citations

h-index: 7

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

2 citations

Melnikov Igor

23 publications, 454 citations, 9 reviews

h-index: 10

N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

1 citation

Dotsenko Viktor

DSc in Chemistry, professor

244 publications, 2 741 citations, 2 reviews

h-index: 22

North Caucasus Federal University

Kuban State University

Research interests

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Heterocyclic compounds

Malononitrile

Selenoamides

Thioamides

1 citation

Zagidullin Almaz

🥼 🤝

PhD in Chemistry

81 publications, 884 citations

h-index: 17

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Asymmetric metal complex catalysis

Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials

Coordination chemistry of phosphorus

Organoelement chemistry

Organophosphorus chemistry

Synthesis of chiral phosphorus-containing ligands

1 citation

Eliseev O

87 publications, 727 citations, 3 reviews

h-index: 17

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Peoples' Friendship University of Russia

1 citation

Kosareva Ekaterina

🥼

PhD in Physics and Mathematics

14 publications, 263 citations

h-index: 7

N.N. Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Research interests

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Nanomaterials

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1 citation

Kononov Leonid

DSc in Chemistry

150 publications, 2 082 citations, 28 reviews

h-index: 25

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

1 citation

Aksenov Aleksandr

🥼 🤝

DSc in Chemistry, professor

243 publications, 2 187 citations, 15 reviews

h-index: 24

North Caucasus Federal University

Research interests

Medicinal Chemistry

Organic Chemistry

1 citation

Sosnovskikh Vyacheslav

DSc in Chemistry, professor

355 publications, 4 721 citations

h-index: 30

Ural Federal University

1 citation

Ilkin Vladimir

PhD in Chemistry

16 publications, 187 citations

h-index: 7

Ural Federal University

Research interests

Catalysis

Heterocyclic compounds

Organic Chemistry

Synthetic Organic Chemistry

1 citation

Krylov Igor

PhD in Chemistry

78 publications, 1 885 citations, 18 reviews

h-index: 25

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Green chemistry

Organic Chemistry

Organic electrochemistry

Organic synthesis

Photochemistry

Plant protection

1 citation

Chaliy Vasiliy

🥼

7 publications, 19 citations

h-index: 3

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Bauman Moscow State Technical University

Research interests

Density functional theory (DFT)

Molecular modeling

1 citation

Tikhomirov Alexander

🥼 🤝

DSc in Chemistry, associate professor

59 publications, 920 citations

h-index: 17

Mendeleev University of Chemical Technology of Russia

Gause Institute of New Antibiotics

Research interests

Medicinal Chemistry

1 citation

Ivanov Andrey

54 publications, 534 citations

h-index: 12

A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

1 citation

Lobanov Nikolay

6 publications, 7 citations

h-index: 2

Lomonosov Moscow State University

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Shaferov A. V. et al. First Example of 1,2,5‐Oxadiazole‐Based Hypergolic Ionic Liquids: a New Class of Potential Energetic Fuels // Chemistry - A European Journal. 2023. Vol. 29. No. 44. e202300948

GOST all authors (up to 50) Copy

Shaferov A. V., Arakelov S. T., Teslenko F. E., Pivkina A. N., Muravyev N. V., Fershtat L. L. First Example of 1,2,5‐Oxadiazole‐Based Hypergolic Ionic Liquids: a New Class of Potential Energetic Fuels // Chemistry - A European Journal. 2023. Vol. 29. No. 44. e202300948

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/chem.202300948

UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202300948

TI - First Example of 1,2,5‐Oxadiazole‐Based Hypergolic Ionic Liquids: a New Class of Potential Energetic Fuels

T2 - Chemistry - A European Journal

AU - Shaferov, Alexander V

AU - Arakelov, Sergey T.

AU - Teslenko, Fedor E

AU - Pivkina, Alla N

AU - Muravyev, Nikita V

AU - Fershtat, Leonid L.

PY - 2023

DA - 2023/07/06

PB - Wiley

IS - 44

VL - 29

PMID - 37216337

SN - 0947-6539

SN - 1521-3765

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2023_Shaferov,

author = {Alexander V Shaferov and Sergey T. Arakelov and Fedor E Teslenko and Alla N Pivkina and Nikita V Muravyev and Leonid L. Fershtat},

title = {First Example of 1,2,5‐Oxadiazole‐Based Hypergolic Ionic Liquids: a New Class of Potential Energetic Fuels},

journal = {Chemistry - A European Journal},

year = {2023},

volume = {29},

publisher = {Wiley},

month = {jul},

url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202300948},

number = {44},

pages = {e202300948},

doi = {10.1002/chem.202300948}

}

Publisher

Wiley

Journal

Chemistry - A European Journal

scimago Q1

wos Q2

SJR

0.981

CiteScore

6.7

Impact factor

3.7

ISSN

09476539 (Print)

15213765 (Electronic)

Labs

Laboratory of Nitrogen-Containing Compounds

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