volume 29 issue 67

Photocatalyc Hydrodecarboxylation of Fatty Acids for Drop‐In Biofuels Production

Jhudson G. L. de Araujo 1
Maria do S. B. da Silva 1
Júlia C C V Bento 1
Amanda M. de Azevêdo 1
Aruzza M. de M. Araújo 1
Aecia S. D. dos Anjos 1
Carlos A. Martínez-Huitle 1
Elisama V Dos Santos 1
Amanda D Gondim 1
Lívia N Cavalcanti 1
Publication typeJournal Article
Publication date2023-10-19
scimago Q1
wos Q2
SJR0.981
CiteScore6.7
Impact factor3.7
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract

A mild, practical, and environmentally friendly method for the hydrodecarboxylation of fatty acids using an acridine‐based photoredox catalyst and thiophenol was developed. Cn‐1 alkanes were synthesized in good to excellent yields (up to 99 %) from C10−C18 saturated fatty acids under visible light irradiation (405 nm). The developed protocol was employed for a mixture of fatty acids obtained from the hydrolysis of Licuri oil, affording a mixture of C9−C17 hydrocarbons in quantitative yield, which demonstrates the potential application of the method to produce drop‐in biofuels.

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GOST |
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GOST Copy
de Araujo J. G. L. et al. Photocatalyc Hydrodecarboxylation of Fatty Acids for Drop‐In Biofuels Production // Chemistry - A European Journal. 2023. Vol. 29. No. 67.
GOST all authors (up to 50) Copy
de Araujo J. G. L., da Silva M. D. S. B., Bento J. C. C. V., de Azevêdo A. M., de M. Araújo A. M., dos Anjos A. S. D., Martínez-Huitle C. A., Dos Santos E. V., Gondim A. D., Cavalcanti L. N. Photocatalyc Hydrodecarboxylation of Fatty Acids for Drop‐In Biofuels Production // Chemistry - A European Journal. 2023. Vol. 29. No. 67.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/chem.202302330
UR - https://doi.org/10.1002/chem.202302330
TI - Photocatalyc Hydrodecarboxylation of Fatty Acids for Drop‐In Biofuels Production
T2 - Chemistry - A European Journal
AU - de Araujo, Jhudson G. L.
AU - da Silva, Maria do S. B.
AU - Bento, Júlia C C V
AU - de Azevêdo, Amanda M.
AU - de M. Araújo, Aruzza M.
AU - dos Anjos, Aecia S. D.
AU - Martínez-Huitle, Carlos A.
AU - Dos Santos, Elisama V
AU - Gondim, Amanda D
AU - Cavalcanti, Lívia N
PY - 2023
DA - 2023/10/19
PB - Wiley
IS - 67
VL - 29
PMID - 37646537
SN - 0947-6539
SN - 1521-3765
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2023_de Araujo,
author = {Jhudson G. L. de Araujo and Maria do S. B. da Silva and Júlia C C V Bento and Amanda M. de Azevêdo and Aruzza M. de M. Araújo and Aecia S. D. dos Anjos and Carlos A. Martínez-Huitle and Elisama V Dos Santos and Amanda D Gondim and Lívia N Cavalcanti},
title = {Photocatalyc Hydrodecarboxylation of Fatty Acids for Drop‐In Biofuels Production},
journal = {Chemistry - A European Journal},
year = {2023},
volume = {29},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/chem.202302330},
number = {67},
doi = {10.1002/chem.202302330}
}