A Trigonal Prismatic Cobalt(II) Complex as a Single Molecule Magnet with a Reduced Contribution from Quantum Tunneling.
Тип публикации: Journal Article
Дата публикации: 2019-04-05
scimago Q2
wos Q3
БС2
SJR: 0.553
CiteScore: 3.6
Impact factor: 2.2
ISSN: 14394235, 14397641
PubMed ID:
30897255
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
Краткое описание
Herein, we report a new trigonal prismatic cobalt(II) complex that behaves as a single molecule magnet. The obtained zero-field splitting, which is also directly accessed by THz-EPR spectroscopy (-102.5 cm-1 ), results in a large magnetization reversal barrier U of 205 cm-1 . Its effective value, however, is much lower (101 cm-1 ), even though there is practically no contribution from quantum tunneling to magnetization relaxation.
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Pavlov A. et al. A Trigonal Prismatic Cobalt(II) Complex as a Single Molecule Magnet with a Reduced Contribution from Quantum Tunneling. // ChemPhysChem. 2019. Vol. 20. No. 8. pp. 1001-1005.
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Pavlov A., Aleshin D. Y., Savkina S. A., Belov A. S., Efimov N. N., Nehrkorn J., Ozerov M., Voloshin Y. Z., Nelyubina Y. V., Novikov V. V. A Trigonal Prismatic Cobalt(II) Complex as a Single Molecule Magnet with a Reduced Contribution from Quantum Tunneling. // ChemPhysChem. 2019. Vol. 20. No. 8. pp. 1001-1005.
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TY - JOUR
DO - 10.1002/cphc.201900219
UR - https://doi.org/10.1002/cphc.201900219
TI - A Trigonal Prismatic Cobalt(II) Complex as a Single Molecule Magnet with a Reduced Contribution from Quantum Tunneling.
T2 - ChemPhysChem
AU - Pavlov, Alexander
AU - Aleshin, Dmitry Y
AU - Savkina, Svetlana A
AU - Belov, Alexander S.
AU - Efimov, Nikolay N.
AU - Nehrkorn, Joscha
AU - Ozerov, M.
AU - Voloshin, Yan Z.
AU - Nelyubina, Yulia V.
AU - Novikov, Valentin V
PY - 2019
DA - 2019/04/05
PB - Wiley
SP - 1001-1005
IS - 8
VL - 20
PMID - 30897255
SN - 1439-4235
SN - 1439-7641
ER -
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@article{2019_Pavlov,
author = {Alexander Pavlov and Dmitry Y Aleshin and Svetlana A Savkina and Alexander S. Belov and Nikolay N. Efimov and Joscha Nehrkorn and M. Ozerov and Yan Z. Voloshin and Yulia V. Nelyubina and Valentin V Novikov},
title = {A Trigonal Prismatic Cobalt(II) Complex as a Single Molecule Magnet with a Reduced Contribution from Quantum Tunneling.},
journal = {ChemPhysChem},
year = {2019},
volume = {20},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/cphc.201900219},
number = {8},
pages = {1001--1005},
doi = {10.1002/cphc.201900219}
}
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MLA
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Pavlov, Alexander, et al. “A Trigonal Prismatic Cobalt(II) Complex as a Single Molecule Magnet with a Reduced Contribution from Quantum Tunneling..” ChemPhysChem, vol. 20, no. 8, Apr. 2019, pp. 1001-1005. https://doi.org/10.1002/cphc.201900219.
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