ChemPhotoChem, volume 1, issue 5, pages 159-163
Understanding Reactivity Patterns in Light-Induced Nitrile Imine Mediated Tetrazole-Ene Cycloadditions
Eva Blasco
1, 2
,
Yuuki Sugawara
1, 2
,
Paul Lederhose
1, 3
,
James P. Blinco
3
,
Christopher Barner‐Kowollik
1, 2, 3
Publication type: Journal Article
Publication date: 2017-01-25
Journal:
ChemPhotoChem
Quartile SCImago
Q1
Quartile WOS
Q3
SJR: 0.854
CiteScore: 5.8
Impact factor: 3
ISSN: 23670932
Organic Chemistry
Physical and Theoretical Chemistry
Analytical Chemistry
Abstract
A rationale for predicting photochemical tetrazole activation in the popular nitrile imine mediated tetrazole–ene cycloaddition (NITEC) reaction, based on a combined theoretical and experimental study, is reported. DFT calculations of three tetrazole derivatives reveal that the efficiency of intersystem crossing is determined by the chromophore moiety. This species is critical in dictating the reactivity of the tetrazoles towards nitrile imine formation, yet mere inspection of the chromophore moiety's absorptivity is insufficient for predicting the tetrazole's photochemical reactivity.
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GOST
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Blasco E. et al. Understanding Reactivity Patterns in Light-Induced Nitrile Imine Mediated Tetrazole-Ene Cycloadditions // ChemPhotoChem. 2017. Vol. 1. No. 5. pp. 159-163.
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Blasco E., Sugawara Y., Lederhose P., Blinco J. P., Kelterer A., Barner‐Kowollik C. Understanding Reactivity Patterns in Light-Induced Nitrile Imine Mediated Tetrazole-Ene Cycloadditions // ChemPhotoChem. 2017. Vol. 1. No. 5. pp. 159-163.
Cite this
RIS
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TY - JOUR
DO - 10.1002/cptc.201600042
UR - https://doi.org/10.1002/cptc.201600042
TI - Understanding Reactivity Patterns in Light-Induced Nitrile Imine Mediated Tetrazole-Ene Cycloadditions
T2 - ChemPhotoChem
AU - Lederhose, Paul
AU - Blasco, Eva
AU - Sugawara, Yuuki
AU - Blinco, James P.
AU - Kelterer, Anne-Marie
AU - Barner‐Kowollik, Christopher
PY - 2017
DA - 2017/01/25
PB - Wiley
SP - 159-163
IS - 5
VL - 1
SN - 2367-0932
ER -
Cite this
BibTex
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@article{2017_Blasco,
author = {Paul Lederhose and Eva Blasco and Yuuki Sugawara and James P. Blinco and Anne-Marie Kelterer and Christopher Barner‐Kowollik},
title = {Understanding Reactivity Patterns in Light-Induced Nitrile Imine Mediated Tetrazole-Ene Cycloadditions},
journal = {ChemPhotoChem},
year = {2017},
volume = {1},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/cptc.201600042},
number = {5},
pages = {159--163},
doi = {10.1002/cptc.201600042}
}
Cite this
MLA
Copy
Blasco, Eva, et al. “Understanding Reactivity Patterns in Light-Induced Nitrile Imine Mediated Tetrazole-Ene Cycloadditions.” ChemPhotoChem, vol. 1, no. 5, Jan. 2017, pp. 159-163. https://doi.org/10.1002/cptc.201600042.