, volume 5 , issue 4 , pages 783-789

The first molecular level monitoring of carbohydrate conversion to 5-hydroxymethylfurfural in ionic liquids. B2O3--an efficient dual-function metal-free promoter for environmentally benign applications.

Elena A Khokhlova ¹

Vadim V. Kachala ²

Valentine P. Ananikov ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences Moscow Russia |

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospekt, 47, Moscow, 119991 (Russia), Fax: (+7) 499-1355328 |

Publication type: Journal Article

Publication date: 2012-02-22

Wiley

ChemSusChem

scimago Q1

wos Q1

SJR: 1.845

CiteScore: 13.1

Impact factor: 6.6

ISSN: 18645631, 1864564X

DOI: 10.1002/cssc.201100670

Copy DOI

PubMed ID: 22359390

General Chemical Engineering

General Materials Science

General Energy

Environmental Chemistry

Abstract

The mechanistic nature of the conversion of carbohydrates to the sustainable platform chemical 5-hydroxymethylfurfural (5-HMF) was revealed at the molecular level. A detailed study of the key sugar units involved in the biomass conversion process has shown that the simple dissolution of fructose in the ionic liquid 1-butyl-3-methylimidazolium chloride significantly changes the anomeric composition and favors the formation of the open fructoketose form. A special NMR approach was developed for the determination of molecular structures and monitoring of chemical reactions directly in ionic liquids. The transformation of glucose to 5-HMF has been followed in situ through the detection of intermediate species. A new environmentally benign, easily available, metal-free promoter with a dual functionality (B(2)O(3)) was developed for carbohydrate conversion to 5-HMF.

Found

8 citations

Galkin Konstantin

🥼 🤝

PhD in Chemistry, associate professor

30 publications, 1 320 citations, 4 reviews

h-index: 16

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

Moscow Polytechnic University

1 citation

Burykina Julia

PhD in Chemistry

53 publications, 1 111 citations, 1 review

h-index: 16

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

1 citation

Redina Elena

🥼 🤝

PhD in Chemistry

43 publications, 617 citations, 46 reviews

h-index: 14

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Green chemistry

Heterogeneous catalysis

Nanoparticles of metal oxides

Organic synthesis

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Khokhlova E. A., Kachala V. V., Ananikov V. P. The first molecular level monitoring of carbohydrate conversion to 5-hydroxymethylfurfural in ionic liquids. B2O3--an efficient dual-function metal-free promoter for environmentally benign applications. // ChemSusChem. 2012. Vol. 5. No. 4. pp. 783-789.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/cssc.201100670

UR - https://doi.org/10.1002/cssc.201100670

TI - The first molecular level monitoring of carbohydrate conversion to 5-hydroxymethylfurfural in ionic liquids. B2O3--an efficient dual-function metal-free promoter for environmentally benign applications.

T2 - ChemSusChem

AU - Khokhlova, Elena A

AU - Kachala, Vadim V.

AU - Ananikov, Valentine P.

PY - 2012

DA - 2012/02/22

PB - Wiley

SP - 783-789

IS - 4

VL - 5

PMID - 22359390

SN - 1864-5631

SN - 1864-564X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2012_Khokhlova,

author = {Elena A Khokhlova and Vadim V. Kachala and Valentine P. Ananikov},

title = {The first molecular level monitoring of carbohydrate conversion to 5-hydroxymethylfurfural in ionic liquids. B2O3--an efficient dual-function metal-free promoter for environmentally benign applications.},

journal = {ChemSusChem},

year = {2012},

volume = {5},

publisher = {Wiley},

month = {feb},

url = {https://doi.org/10.1002/cssc.201100670},

number = {4},

pages = {783--789},

doi = {10.1002/cssc.201100670}

}

MLA

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Khokhlova, Elena A., et al. “The first molecular level monitoring of carbohydrate conversion to 5-hydroxymethylfurfural in ionic liquids. B2O3--an efficient dual-function metal-free promoter for environmentally benign applications..” ChemSusChem, vol. 5, no. 4, Feb. 2012, pp. 783-789. https://doi.org/10.1002/cssc.201100670.