Towards Improved Biorefinery Technologies: 5-Methylfurfural as a Versatile C6 Platform for Biofuels Development.
Publication type: Journal Article
Publication date: 2018-11-27
scimago Q1
wos Q1
SJR: 1.845
CiteScore: 13.1
Impact factor: 6.6
ISSN: 18645631, 1864564X
PubMed ID:
30315683
General Chemical Engineering
General Materials Science
General Energy
Environmental Chemistry
Abstract
Low chemical stability and high oxygen content limit utilization of the bio-based platform chemical 5-(hydroxymethyl)furfural (HMF) in biofuels development. In this work, Lewis-acid-catalyzed conversion of renewable 6-deoxy sugars leading to formation of more stable 5-methylfurfural (MF) is carried out with high selectivity. Besides its higher stability, MF is a deoxygenated analogue of HMF with increased C/O ratio. A highly selective synthesis of the innovative liquid biofuel 2,5-dimethylfuran starting from MF under mild conditions is described. The superior synthetic utility of MF against HMF in benzoin and aldol condensation reactions leading to long-chain alkane precursors is demonstrated.
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Metrics
56
Total citations:
56
Citations from 2025:
9
(16.07%)
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MLA
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GOST
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Galkin K. I., Ananikov V. P. Towards Improved Biorefinery Technologies: 5-Methylfurfural as a Versatile C6 Platform for Biofuels Development. // ChemSusChem. 2018. Vol. 12. No. 1. pp. 185-189.
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Galkin K. I., Ananikov V. P. Towards Improved Biorefinery Technologies: 5-Methylfurfural as a Versatile C6 Platform for Biofuels Development. // ChemSusChem. 2018. Vol. 12. No. 1. pp. 185-189.
Cite this
RIS
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TY - JOUR
DO - 10.1002/cssc.201802126
UR - https://doi.org/10.1002/cssc.201802126
TI - Towards Improved Biorefinery Technologies: 5-Methylfurfural as a Versatile C6 Platform for Biofuels Development.
T2 - ChemSusChem
AU - Galkin, Konstantin I
AU - Ananikov, Valentine P.
PY - 2018
DA - 2018/11/27
PB - Wiley
SP - 185-189
IS - 1
VL - 12
PMID - 30315683
SN - 1864-5631
SN - 1864-564X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2018_Galkin,
author = {Konstantin I Galkin and Valentine P. Ananikov},
title = {Towards Improved Biorefinery Technologies: 5-Methylfurfural as a Versatile C6 Platform for Biofuels Development.},
journal = {ChemSusChem},
year = {2018},
volume = {12},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/cssc.201802126},
number = {1},
pages = {185--189},
doi = {10.1002/cssc.201802126}
}
Cite this
MLA
Copy
Galkin, Konstantin I., and Valentine P. Ananikov. “Towards Improved Biorefinery Technologies: 5-Methylfurfural as a Versatile C6 Platform for Biofuels Development..” ChemSusChem, vol. 12, no. 1, Nov. 2018, pp. 185-189. https://doi.org/10.1002/cssc.201802126.