ChemSusChem, volume 12, issue 13, pages 3172-3177

Combined CO ₂ Capture and Hydrogenation to Methanol: Amine Immobilization Enables Easy Recycling of Active Elements

Sayan Kar ¹

Alain Goeppert ¹

G. K. Surya Prakash ¹

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Loker Hydrocarbon Research Institute and Department of ChemistryUniversity of Southern California University Park Los Angeles California 90089-1661 USA |

Publication type: Journal Article

Publication date: 2019-04-04

Wiley

Journal: ChemSusChem

Quartile SCImago

Quartile WOS

Impact factor: 8.4

ISSN: 18645631, 1864564X

DOI: 10.1002/cssc.201900324

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General Chemical Engineering

General Materials Science

General Energy

Environmental Chemistry

Abstract

Amines were immobilized onto solid supports and employed for tandem CO2 capture and conversion to CH3 OH using homogeneous hydrogenation catalysts. The hydrogenation proceeded through the formation of formamide intermediates. After hydrogenation, the immobilized amines were easily filtered and collected to be reused. The catalyst and methanol were recovered from the filtrate. Covalently-attached (to polymer support or silica) amine functionalities displayed the highest recycling potential with almost no leaching under the hydrogenation reaction conditions. Using polyethylenimine grafted onto a solid-silica support, the catalyst and amine were successfully recycled, and CO2 (either pure or from the air) was efficiently captured and converted to CH3 OH over multiple cycles.

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Citations by journals

	1 2 3 4
ChemSusChem	ChemSusChem, 4, 7.27% ChemSusChem 4 publications, 7.27%
Journal of CO2 Utilization	Journal of CO2 Utilization, 3, 5.45% Journal of CO2 Utilization 3 publications, 5.45%
ACS Catalysis	ACS Catalysis, 3, 5.45% ACS Catalysis 3 publications, 5.45%
Catalysts	Catalysts, 2, 3.64% Catalysts 2 publications, 3.64%
Molecules	Molecules, 2, 3.64% Molecules 2 publications, 3.64%
ChemCatChem	ChemCatChem, 2, 3.64% ChemCatChem 2 publications, 3.64%
Journal of the American Chemical Society	Journal of the American Chemical Society, 2, 3.64% Journal of the American Chemical Society 2 publications, 3.64%
Langmuir	Langmuir, 2, 3.64% Langmuir 2 publications, 3.64%
Green Chemistry	Green Chemistry, 1, 1.82% Green Chemistry 1 publication, 1.82%
Energies	Energies, 1, 1.82% Energies 1 publication, 1.82%
Frontiers in Energy Research	Frontiers in Energy Research, 1, 1.82% Frontiers in Energy Research 1 publication, 1.82%
Nature Communications	Nature Communications, 1, 1.82% Nature Communications 1 publication, 1.82%
International Journal of Minerals, Metallurgy and Materials	International Journal of Minerals, Metallurgy and Materials, 1, 1.82% International Journal of Minerals, Metallurgy and Materials 1 publication, 1.82%
Chem Catalysis	Chem Catalysis, 1, 1.82% Chem Catalysis 1 publication, 1.82%
Journal of Organometallic Chemistry	Journal of Organometallic Chemistry, 1, 1.82% Journal of Organometallic Chemistry 1 publication, 1.82%
Progress in Energy and Combustion Science	Progress in Energy and Combustion Science, 1, 1.82% Progress in Energy and Combustion Science 1 publication, 1.82%
Joule	Joule, 1, 1.82% Joule 1 publication, 1.82%
Energy and Environmental Science	Energy and Environmental Science, 1, 1.82% Energy and Environmental Science 1 publication, 1.82%
Current Opinion in Green and Sustainable Chemistry	Current Opinion in Green and Sustainable Chemistry, 1, 1.82% Current Opinion in Green and Sustainable Chemistry 1 publication, 1.82%
Tetrahedron	Tetrahedron, 1, 1.82% Tetrahedron 1 publication, 1.82%
EnergyChem	EnergyChem, 1, 1.82% EnergyChem 1 publication, 1.82%
Molecular Catalysis	Molecular Catalysis, 1, 1.82% Molecular Catalysis 1 publication, 1.82%
Science of the Total Environment	Science of the Total Environment, 1, 1.82% Science of the Total Environment 1 publication, 1.82%
Journal of Catalysis	Journal of Catalysis, 1, 1.82% Journal of Catalysis 1 publication, 1.82%
Angewandte Chemie	Angewandte Chemie, 1, 1.82% Angewandte Chemie 1 publication, 1.82%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 1.82% Angewandte Chemie - International Edition 1 publication, 1.82%
Accounts of Chemical Research	Accounts of Chemical Research, 1, 1.82% Accounts of Chemical Research 1 publication, 1.82%
ACS Sustainable Chemistry and Engineering	ACS Sustainable Chemistry and Engineering, 1, 1.82% ACS Sustainable Chemistry and Engineering 1 publication, 1.82%
ACS Energy Letters	ACS Energy Letters, 1, 1.82% ACS Energy Letters 1 publication, 1.82%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12 14 16
Elsevier	Elsevier, 15, 27.27% Elsevier 15 publications, 27.27%
American Chemical Society (ACS)	American Chemical Society (ACS), 12, 21.82% American Chemical Society (ACS) 12 publications, 21.82%
Wiley	Wiley, 10, 18.18% Wiley 10 publications, 18.18%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 5, 9.09% Royal Society of Chemistry (RSC) 5 publications, 9.09%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 5, 9.09% Multidisciplinary Digital Publishing Institute (MDPI) 5 publications, 9.09%
Frontiers Media S.A.	Frontiers Media S.A., 1, 1.82% Frontiers Media S.A. 1 publication, 1.82%
Springer Nature	Springer Nature, 1, 1.82% Springer Nature 1 publication, 1.82%
University of Science and Technology Beijing	University of Science and Technology Beijing, 1, 1.82% University of Science and Technology Beijing 1 publication, 1.82%
Pleiades Publishing	Pleiades Publishing, 1, 1.82% Pleiades Publishing 1 publication, 1.82%
Materials Research Society	Materials Research Society, 1, 1.82% Materials Research Society 1 publication, 1.82%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.82% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.82%
	2 4 6 8 10 12 14 16

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Kar S., Goeppert A., Surya Prakash G. K. Combined CO 2 Capture and Hydrogenation to Methanol: Amine Immobilization Enables Easy Recycling of Active Elements // ChemSusChem. 2019. Vol. 12. No. 13. pp. 3172-3177.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/cssc.201900324

UR - https://doi.org/10.1002/cssc.201900324

TI - Combined CO 2 Capture and Hydrogenation to Methanol: Amine Immobilization Enables Easy Recycling of Active Elements

T2 - ChemSusChem

AU - Surya Prakash, G. K.

AU - Kar, Sayan

AU - Goeppert, Alain

PY - 2019

DA - 2019/04/04 00:00:00

PB - Wiley

SP - 3172-3177

IS - 13

VL - 12

SN - 1864-5631

SN - 1864-564X

ER -

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BibTex Copy

@article{2019_Kar,

author = {G. K. Surya Prakash and Sayan Kar and Alain Goeppert},

title = {Combined CO 2 Capture and Hydrogenation to Methanol: Amine Immobilization Enables Easy Recycling of Active Elements},

journal = {ChemSusChem},

year = {2019},

volume = {12},

publisher = {Wiley},

month = {apr},

url = {https://doi.org/10.1002/cssc.201900324},

number = {13},

pages = {3172--3177},

doi = {10.1002/cssc.201900324}

}

MLA

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Kar, Sayan, et al. “Combined CO 2 Capture and Hydrogenation to Methanol: Amine Immobilization Enables Easy Recycling of Active Elements.” ChemSusChem, vol. 12, no. 13, Apr. 2019, pp. 3172-3177. https://doi.org/10.1002/cssc.201900324.

Found error?

Publisher

Wiley

Journal

ChemSusChem

Quartile SCImago

Quartile WOS

Impact factor

8.4

ISSN

18645631 (Print)
1864564X (Electronic)