European Journal of Inorganic Chemistry

, volume 2007 , issue 30 , pages 4800-4807

Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes

Alexander G. Martynov ^{1, 2}

O. V. Zubareva ¹

Yulia G. Gorbunova ^{1, 2}

Sergey G. Sakharov ²

Sergey E. Nefedov ²

Fedor Dolgushin ³

Aslan Tsivadze ^{1, 2}

Hide authors affiliations Show authors affiliations: 3 affiliations

A. N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS Leninsky Prosp. 31, Moscow 119991, Russia |

N. S. Kurnakov Institute of General and Inorganic Chemistry RAS Leninsky Prosp. 31, Moscow 119991, Russia |

A. N. Nesmeyanov Institute of Organoelement Compounds RAS Moscow, Vavilova str. 28, Moscow 119991, Russia |

Publication type: Journal Article

Publication date: 2007-10-01

Wiley

European Journal of Inorganic Chemistry

scimago Q2

wos Q3

SJR: 0.459

CiteScore: 3.9

Impact factor: 2.0

ISSN: 14341948, 10990682

DOI: 10.1002/ejic.200700489

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Inorganic Chemistry

Abstract

A novel synthetic approach towards heteroleptic triple‐decker crown‐phthalocyaninato complexes [(15C5)₄Pc]M[(15C5)₄Pc]M(Pc) and (Pc)M[(15C5)₄Pc]M(Pc) [where (15C5)₄Pc^2– = 2,3,9,10,16,17,24,25‐tetrakis(15‐crown‐5)phthalocyaninato dianion; Pc^2– = phthalocyaninato dianion; M = Sm, Tb, Dy, Tm and Y] has been developed. It utilises the application of diphthalocyaninatolanthanum, La(Pc)₂, as a new source of the phthalocyaninato dianion instead of well known Li₂(Pc). In contrast to the highly hygroscopic Li₂(Pc), La(Pc)₂ is quite air‐stable and its use allowed a significant decrease in reaction times. All the synthesised complexes were characterised by UV/Vis and ¹H NMR spectroscopy as well as MALDI TOF mass spectrometry. The X‐ray structure of heteroleptic triple‐decker crown‐phthalocyaninato (Pc)Sm[(15C5)₄Pc]Sm(Pc) was determined. These new heteroleptic phthalocyaninato complexes are interesting because of their potential as components in new supramolecular materials. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

Found

21 citations

Gorbunova Yuliya

DSc in Chemistry, professor, full member of the Russian Academy of Sciences

284 publications, 4 382 citations, 65 reviews

h-index: 34

Lomonosov Moscow State University

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Lanthanides

Supramolecular chemistry

Tetrapyrrolic compounds

15 citations

Martynov Alexander

🥼 🤝

DSc in Chemistry, associate member of the Russian Academy of Sciences

122 publications, 2 029 citations, 63 reviews

h-index: 25

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Research interests

Chemistry

Coordination Chemistry

Supramolecular chemistry

8 citations

Birin Kirill

🥼 🤝

DSc in Chemistry

95 publications, 1 187 citations, 2 reviews

h-index: 19

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

MIREA — Russian Technological University

National Research University Higher School of Economics

Research interests

Catalysis

Coordination Chemistry

Green chemistry

Hybrid materials

Inorganic Chemistry

Metal-organic coordination polymers

NMR spectroscopy

Organic Chemistry

Organoelement chemistry

3 citations

Selektor Sofiya

🥼 🤝

DSc in Chemistry, associate professor

71 publications, 815 citations, 1 review

h-index: 16

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Non-covalent Interactions

Physical Chemistry

Supramolecular chemistry

1 citation

Ivanov Vladimir

🥼

DSc in Chemistry, full member of the Russian Academy of Sciences

511 publications, 6 728 citations, 137 reviews

h-index: 37

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Lomonosov Moscow State University

National Research University Higher School of Economics

Solid state chemistry

1 citation

Khrustalev Victor

DSc in Chemistry, professor, professor of the Russian Academy of Sciences

324 publications, 4 021 citations, 4 reviews

h-index: 30

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Peoples' Friendship University of Russia

1 citation

Medved’ko Aleksei

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PhD in Chemistry

62 publications, 730 citations, 8 reviews

h-index: 14

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Photochemistry Center

1 citation

Faraonov Maxim

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PhD in Chemistry

59 publications, 423 citations, 2 reviews

h-index: 12

Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

1 citation

Abkhalimov Evgeny

PhD in Chemistry

49 publications, 529 citations

h-index: 11

A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

1 citation

Koshelev Daniil

🤝

17 publications, 186 citations, 10 reviews

h-index: 8

Lomonosov Moscow State University

1 citation

Vashurin Arthur

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DSc in Chemistry, professor

109 publications, 880 citations, 47 reviews

h-index: 16

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Lomonosov Moscow State University

Research interests

Complex formation

Spectroscopy

1 citation

Botnar Anna

PhD in Chemistry

34 publications, 219 citations

h-index: 8

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Martynov A. G. et al. Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes // European Journal of Inorganic Chemistry. 2007. Vol. 2007. No. 30. pp. 4800-4807.

GOST all authors (up to 50) Copy

Martynov A. G., Zubareva O. V., Gorbunova Y. G., Sakharov S. G., Nefedov S. E., Dolgushin F., Tsivadze A. Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes // European Journal of Inorganic Chemistry. 2007. Vol. 2007. No. 30. pp. 4800-4807.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/ejic.200700489

UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200700489

TI - Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes

T2 - European Journal of Inorganic Chemistry

AU - Martynov, Alexander G.

AU - Zubareva, O. V.

AU - Gorbunova, Yulia G.

AU - Sakharov, Sergey G.

AU - Nefedov, Sergey E.

AU - Dolgushin, Fedor

AU - Tsivadze, Aslan

PY - 2007

DA - 2007/10/01

PB - Wiley

SP - 4800-4807

IS - 30

VL - 2007

SN - 1434-1948

SN - 1099-0682

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2007_Martynov,

author = {Alexander G. Martynov and O. V. Zubareva and Yulia G. Gorbunova and Sergey G. Sakharov and Sergey E. Nefedov and Fedor Dolgushin and Aslan Tsivadze},

title = {Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes},

journal = {European Journal of Inorganic Chemistry},

year = {2007},

volume = {2007},

publisher = {Wiley},

month = {oct},

url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200700489},

number = {30},

pages = {4800--4807},

doi = {10.1002/ejic.200700489}

}

MLA

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MLA Copy

Martynov, Alexander G., et al. “Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes.” European Journal of Inorganic Chemistry, vol. 2007, no. 30, Oct. 2007, pp. 4800-4807. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200700489.

Publisher

Wiley

Journal

European Journal of Inorganic Chemistry

scimago Q2

wos Q3

SJR

0.459

CiteScore

3.9

Impact factor

2.0

ISSN

14341948 (Print)

10990682 (Electronic)

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Laboratory of new Physical and Chemical Problems

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