Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes
Тип публикации: Journal Article
Дата публикации: 2007-10-01
scimago Q2
wos Q3
БС2
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Краткое описание
A novel synthetic approach towards heteroleptic triple‐decker crown‐phthalocyaninato complexes [(15C5)4Pc]M[(15C5)4Pc]M(Pc) and (Pc)M[(15C5)4Pc]M(Pc) [where (15C5)4Pc2– = 2,3,9,10,16,17,24,25‐tetrakis(15‐crown‐5)phthalocyaninato dianion; Pc2– = phthalocyaninato dianion; M = Sm, Tb, Dy, Tm and Y] has been developed. It utilises the application of diphthalocyaninatolanthanum, La(Pc)2, as a new source of the phthalocyaninato dianion instead of well known Li2(Pc). In contrast to the highly hygroscopic Li2(Pc), La(Pc)2 is quite air‐stable and its use allowed a significant decrease in reaction times. All the synthesised complexes were characterised by UV/Vis and 1H NMR spectroscopy as well as MALDI TOF mass spectrometry. The X‐ray structure of heteroleptic triple‐decker crown‐phthalocyaninato (Pc)Sm[(15C5)4Pc]Sm(Pc) was determined. These new heteroleptic phthalocyaninato complexes are interesting because of their potential as components in new supramolecular materials. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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Martynov A. G. et al. Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes // European Journal of Inorganic Chemistry. 2007. Vol. 2007. No. 30. pp. 4800-4807.
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Martynov A. G., Zubareva O. V., Gorbunova Y. G., Sakharov S. G., Nefedov S. E., Dolgushin F., Tsivadze A. Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes // European Journal of Inorganic Chemistry. 2007. Vol. 2007. No. 30. pp. 4800-4807.
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TY - JOUR
DO - 10.1002/ejic.200700489
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200700489
TI - Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes
T2 - European Journal of Inorganic Chemistry
AU - Martynov, Alexander G.
AU - Zubareva, O. V.
AU - Gorbunova, Yulia G.
AU - Sakharov, Sergey G.
AU - Nefedov, Sergey E.
AU - Dolgushin, Fedor
AU - Tsivadze, Aslan
PY - 2007
DA - 2007/10/01
PB - Wiley
SP - 4800-4807
IS - 30
VL - 2007
SN - 1434-1948
SN - 1099-0682
ER -
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@article{2007_Martynov,
author = {Alexander G. Martynov and O. V. Zubareva and Yulia G. Gorbunova and Sergey G. Sakharov and Sergey E. Nefedov and Fedor Dolgushin and Aslan Tsivadze},
title = {Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes},
journal = {European Journal of Inorganic Chemistry},
year = {2007},
volume = {2007},
publisher = {Wiley},
month = {oct},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200700489},
number = {30},
pages = {4800--4807},
doi = {10.1002/ejic.200700489}
}
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Martynov, Alexander G., et al. “Diphthalocyaninatolanthanum as a new phthalocyaninato-dianion donor for the synthesis of heteroleptic triple-decker rare earth element crown- phthalocyaninato complexes.” European Journal of Inorganic Chemistry, vol. 2007, no. 30, Oct. 2007, pp. 4800-4807. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200700489.
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