Energetic Materials Trends in 5‐ and 6‐Membered Cyclic Peroxides Containing Hydroperoxy and Hydroxy Substituents
Publication type: Journal Article
Publication date: 2016-09-28
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
Ten peroxide compounds based upon the 3,6-di(hydroperoxy)-1,2-dioxane, 2-hydroxy-6-hydroperoxy-1,2-dioxane, 3,5-di(hydroperoxy)-1,2-dioxolane, and 3-hydroxy-5-hydroperoxy-1,2-dioxolane skeletons have been synthesized, structurally characterized, and fully evaluated for their energetic materials properties. The solid state structures of these compounds are dominated by hydrogen bonding interactions involving the hydroperoxy and hydroxy groups. Energetic materials testing shows that most of the compounds are highly sensitive toward impact and friction, with similar properties to highly sensitive peroxides such as triacetone triperoxide. 3,5-Diethyl-5-hydroperoxy-1,2-dioxolan-3-ol (3b) and 3,5-dimethyl-5-hydroperoxy-1,2-dioxolan-3-ol (5b) have lower impact and friction sensitivities than the other compounds, with values that are appropriate for use as primary explosives.
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Gamage N. D. H. et al. Energetic Materials Trends in 5‐ and 6‐Membered Cyclic Peroxides Containing Hydroperoxy and Hydroxy Substituents // European Journal of Inorganic Chemistry. 2016. Vol. 2016. No. 31. pp. 5036-5043.
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Gamage N. D. H., Stiasny B., Kratz E. G., Stierstorfer J., MARTIN P. D., Cisneros G. A., Klapötke T. M., Winter C. H. Energetic Materials Trends in 5‐ and 6‐Membered Cyclic Peroxides Containing Hydroperoxy and Hydroxy Substituents // European Journal of Inorganic Chemistry. 2016. Vol. 2016. No. 31. pp. 5036-5043.
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TY - JOUR
DO - 10.1002/ejic.201600767
UR - https://doi.org/10.1002/ejic.201600767
TI - Energetic Materials Trends in 5‐ and 6‐Membered Cyclic Peroxides Containing Hydroperoxy and Hydroxy Substituents
T2 - European Journal of Inorganic Chemistry
AU - Gamage, Nipuni Dhanesha H
AU - Stiasny, Benedikt
AU - Kratz, Eric G
AU - Stierstorfer, Jörg
AU - MARTIN, Philip D.
AU - Cisneros, G. Andrés
AU - Klapötke, Thomas M.
AU - Winter, Charles H.
PY - 2016
DA - 2016/09/28
PB - Wiley
SP - 5036-5043
IS - 31
VL - 2016
SN - 1434-1948
SN - 1099-0682
ER -
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BibTex (up to 50 authors)
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@article{2016_Gamage,
author = {Nipuni Dhanesha H Gamage and Benedikt Stiasny and Eric G Kratz and Jörg Stierstorfer and Philip D. MARTIN and G. Andrés Cisneros and Thomas M. Klapötke and Charles H. Winter},
title = {Energetic Materials Trends in 5‐ and 6‐Membered Cyclic Peroxides Containing Hydroperoxy and Hydroxy Substituents},
journal = {European Journal of Inorganic Chemistry},
year = {2016},
volume = {2016},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/ejic.201600767},
number = {31},
pages = {5036--5043},
doi = {10.1002/ejic.201600767}
}
Cite this
MLA
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Gamage, Nipuni Dhanesha H., et al. “Energetic Materials Trends in 5‐ and 6‐Membered Cyclic Peroxides Containing Hydroperoxy and Hydroxy Substituents.” European Journal of Inorganic Chemistry, vol. 2016, no. 31, Sep. 2016, pp. 5036-5043. https://doi.org/10.1002/ejic.201600767.