Wiley
European Journal of Inorganic Chemistry
,  volume 2017 ,  issue 3 ,  pages 704-712

Copper(II), Nickel(II), and Cobalt(II)/(III) Self‐Assembled Polynuclear Complexes of Bis[(pyridin‐2‐yl)‐1,2,4‐triazol‐3‐yl]]methane

Alexey A. Gusev 1
, 
Alexey N Gusev 2
, 
Victor F. Shulgin 1, 2
, 
Irina O Ryush 1, 2
, 
Miki Hasegawa 3
, 
Mikhail A. Kiskin 4
, 
Nikolay N. Efimov 4
, 
Konstantin A. Lyssenko 4
, 
Igor L. Eremenko 5
, 
Wolfgang Linert 6, 7
1
 
2
 
3
 
4
 
5
 
6
 
7
 
Publication type: Journal Article
Publication date: 2017-01-18
Wiley
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract

The reactions of bis[(pyridin‐2‐yl)‐1,2,4‐triazol‐3‐yl]methane (H2L) with copper(II), nickel(II), and cobalt(II) salts afford a series of unusual structures; among them are the homoleptic binuclear complexes [Ni2(H2L)2(H2O)4](NO3)4·6H2O (1) and [Ni2(H2L)2Cl2]Cl2·4H2O·2C4H8O2 (2), the octanuclear complex [Ni8(H2L)12](NO3)16·21H2O (3), and the tetranuclear complexes [Cu4(HL)4](ClO4)4·C2H5OH·3H2O (4), [Co4(HL)2(H2L)2(H2O)4](NO3)8·C2H5OH·6H2O (5), and [Co4(HL)2(H2L)2(H2O)4]·(ClO4)8·8H2O (6). All these compounds have been characterized by different techniques, such as elemental analysis, electrospray mass spectrometry (ES‐MS), UV/Vis spectroscopy, X‐ray structural analyses, and magnetic measurements. It was found that the nature of the cation and the metal/ligand ratio have a substantial impact on the coordination geometries of the unique complexes. The magnetic properties of compounds 1 and 2 show the presence of intramolecular ferromagnetic exchange interactions (J = +2.3 and +15.2 cm–1) combined with intermolecular antiferromagnetic coupling. Complexes 3, 5, and 6 show weak intramolecular antiferromagnetic interactions, while complex 4 shows quite strong antiferromagnetic behavior (J = –53.7 cm–1).

Found 
Found 
3 citations
Kiskin Mikhail
🥼 🤝
DSc in Chemistry, professor
407 publications,  5 037 citations
h-index: 31
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Research interests
Magnets
Nanoparticles
2 citations
Eremenko Igor
DSc in Chemistry, professor, full member of the Russian Academy of Sciences 
674 publications,  7 718 citations,  29 reviews
h-index: 35
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
2 citations
Lyssenko Konstantin
🥼 🤝
DSc in Chemistry, professor
898 publications,  15 140 citations,  2 reviews
h-index: 50
Lomonosov Moscow State University
Lomonosov Moscow State University
National Research University Higher School of Economics
National Research University Higher School of Economics
Research interests
Supramolecular chemistry
1 citation
Tarasenko Maria
PhD in Chemistry
42 publications,  361 citations
h-index: 11
Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences
Northwestern University
Northwestern University
Research interests
Rare Earth elements

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Gusev A. N. et al. Copper(II), Nickel(II), and Cobalt(II)/(III) Self‐Assembled Polynuclear Complexes of Bis[(pyridin‐2‐yl)‐1,2,4‐triazol‐3‐yl]]methane // European Journal of Inorganic Chemistry. 2017. Vol. 2017. No. 3. pp. 704-712.
GOST all authors (up to 50) Copy
Gusev A. A., Gusev A. N., Shulgin V. F., Ryush I. O., Hasegawa M., Kiskin M. A., Efimov N. N., Lyssenko K. A., Eremenko I. L., Linert W. Copper(II), Nickel(II), and Cobalt(II)/(III) Self‐Assembled Polynuclear Complexes of Bis[(pyridin‐2‐yl)‐1,2,4‐triazol‐3‐yl]]methane // European Journal of Inorganic Chemistry. 2017. Vol. 2017. No. 3. pp. 704-712.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/ejic.201601107
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201601107
TI - Copper(II), Nickel(II), and Cobalt(II)/(III) Self‐Assembled Polynuclear Complexes of Bis[(pyridin‐2‐yl)‐1,2,4‐triazol‐3‐yl]]methane
T2 - European Journal of Inorganic Chemistry
AU - Gusev, Alexey A.
AU - Gusev, Alexey N
AU - Shulgin, Victor F.
AU - Ryush, Irina O
AU - Hasegawa, Miki
AU - Kiskin, Mikhail A.
AU - Efimov, Nikolay N.
AU - Lyssenko, Konstantin A.
AU - Eremenko, Igor L.
AU - Linert, Wolfgang
PY - 2017
DA - 2017/01/18
PB - Wiley
SP - 704-712
IS - 3
VL - 2017
SN - 1434-1948
SN - 1099-0682
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Gusev,
author = {Alexey A. Gusev and Alexey N Gusev and Victor F. Shulgin and Irina O Ryush and Miki Hasegawa and Mikhail A. Kiskin and Nikolay N. Efimov and Konstantin A. Lyssenko and Igor L. Eremenko and Wolfgang Linert},
title = {Copper(II), Nickel(II), and Cobalt(II)/(III) Self‐Assembled Polynuclear Complexes of Bis[(pyridin‐2‐yl)‐1,2,4‐triazol‐3‐yl]]methane},
journal = {European Journal of Inorganic Chemistry},
year = {2017},
volume = {2017},
publisher = {Wiley},
month = {jan},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201601107},
number = {3},
pages = {704--712},
doi = {10.1002/ejic.201601107}
}
MLA
Cite this
MLA Copy
Gusev, Alexey N., et al. “Copper(II), Nickel(II), and Cobalt(II)/(III) Self‐Assembled Polynuclear Complexes of Bis[(pyridin‐2‐yl)‐1,2,4‐triazol‐3‐yl]]methane.” European Journal of Inorganic Chemistry, vol. 2017, no. 3, Jan. 2017, pp. 704-712. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201601107.