Crystallization Pathways of Cerium(IV) Phosphates Under Hydrothermal Conditions: A Search for New Phases with a Tunnel Structure
Taisiya O Shekunova
1, 2, 3, 4
,
Taisiya O. Kozlova
2, 4
,
Andrey V Mironov
2, 4
,
Alexander E. Baranchikov
1, 2, 3, 4
,
Alexey D. Yapryntsev
1, 3
,
Arsen A Galstyan
2, 4
,
Nikolay P. Simonenko
1, 3
,
Andrey A Gippius
2, 4, 5, 6
,
Sergey V Zhurenko
2, 4, 5, 6
,
Tatyana B. Shatalova
2, 4
,
Lyudmila S Skogareva
1, 3
,
Vladimir K. Ivanov
1, 3, 7, 8
Publication type: Journal Article
Publication date: 2019-01-17
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
Hydrothermal crystallization pathways of amorphous ceric phosphate gels were found to be determined by the ammonia concentration in a reaction medium. This allows for highly selective hydrothermal synthesis of various finely crystalline ceric phosphates, including Ce(PO4)(HPO4)0.5(H2O)0.5, (NH4)2Ce(PO4)2(H2O), and previously unknown NH4Ce2(PO4)3. The structure of the latter compound was solved from powder X‐ray diffraction data. It appeared to be isostructural to ammonium thorium phosphate, NH4Th2(PO4)3; in this crystal structure, large channels (5.07 × 3.79 Å) located along the c‐axis are occupied by NH4+ ions.
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Citations from 2024:
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Shekunova T. O. et al. Crystallization Pathways of Cerium(IV) Phosphates Under Hydrothermal Conditions: A Search for New Phases with a Tunnel Structure // European Journal of Inorganic Chemistry. 2019. Vol. 2019. No. 27. pp. 3242-3248.
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Shekunova T. O., Kozlova T. O., Mironov A. V., Baranchikov A. E., Yapryntsev A. D., Galstyan A. A., Simonenko N. P., Gippius A. A., Zhurenko S. V., Shatalova T. B., Skogareva L. S., Ivanov V. K. Crystallization Pathways of Cerium(IV) Phosphates Under Hydrothermal Conditions: A Search for New Phases with a Tunnel Structure // European Journal of Inorganic Chemistry. 2019. Vol. 2019. No. 27. pp. 3242-3248.
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TY - JOUR
DO - 10.1002/ejic.201801182
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201801182
TI - Crystallization Pathways of Cerium(IV) Phosphates Under Hydrothermal Conditions: A Search for New Phases with a Tunnel Structure
T2 - European Journal of Inorganic Chemistry
AU - Shekunova, Taisiya O
AU - Kozlova, Taisiya O.
AU - Mironov, Andrey V
AU - Baranchikov, Alexander E.
AU - Yapryntsev, Alexey D.
AU - Galstyan, Arsen A
AU - Simonenko, Nikolay P.
AU - Gippius, Andrey A
AU - Zhurenko, Sergey V
AU - Shatalova, Tatyana B.
AU - Skogareva, Lyudmila S
AU - Ivanov, Vladimir K.
PY - 2019
DA - 2019/01/17
PB - Wiley
SP - 3242-3248
IS - 27
VL - 2019
SN - 1434-1948
SN - 1099-0682
ER -
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@article{2019_Shekunova,
author = {Taisiya O Shekunova and Taisiya O. Kozlova and Andrey V Mironov and Alexander E. Baranchikov and Alexey D. Yapryntsev and Arsen A Galstyan and Nikolay P. Simonenko and Andrey A Gippius and Sergey V Zhurenko and Tatyana B. Shatalova and Lyudmila S Skogareva and Vladimir K. Ivanov},
title = {Crystallization Pathways of Cerium(IV) Phosphates Under Hydrothermal Conditions: A Search for New Phases with a Tunnel Structure},
journal = {European Journal of Inorganic Chemistry},
year = {2019},
volume = {2019},
publisher = {Wiley},
month = {jan},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201801182},
number = {27},
pages = {3242--3248},
doi = {10.1002/ejic.201801182}
}
Cite this
MLA
Copy
Shekunova, Taisiya O., et al. “Crystallization Pathways of Cerium(IV) Phosphates Under Hydrothermal Conditions: A Search for New Phases with a Tunnel Structure.” European Journal of Inorganic Chemistry, vol. 2019, no. 27, Jan. 2019, pp. 3242-3248. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201801182.