European Journal of Inorganic Chemistry

, том 2019 , издание 45 , страницы 4855-4861

Luminescent Ag ^I Complexes with 2,2′‐Bipyridine Derivatives Featuring [Ag‐(CF ₃ ) ₂ Pyrazolate] ₄ Units

Тип публикации: Journal Article

Дата публикации: 2019-12-02

Wiley

European Journal of Inorganic Chemistry

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SJR: 0.459

CiteScore: 3.9

Impact factor: 2

ISSN: 14341948, 10990682

DOI: 10.1002/ejic.201901050

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Inorganic Chemistry

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The tetranuclear silver(I) 3,5‐bis(trifluoromethyl)pyrazolate adducts with 2,2′‐bipyridine derivatives were prepared by the reaction of trinuclear metal complex with the diimines. It was shown that the product structure depends on the reagents ratio: mono‐ and bisdiimine complexes were synthesized. Compounds obtained possess green phosphorescence in the solid state. The short intramolecular Ag···Ag distances (≤ 3 Å) make possible electronic communication between the metal atoms which leads to the dual emissive behavior mainly due to the ³LC phosphorescence with the impact of ³MLCT. The behavior observed was rationalized by the TD‐DFT study.

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Emashova S. K. et al. Luminescent Ag I Complexes with 2,2′‐Bipyridine Derivatives Featuring [Ag‐(CF 3 ) 2 Pyrazolate] 4 Units // European Journal of Inorganic Chemistry. 2019. Vol. 2019. No. 45. pp. 4855-4861.

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Emashova S. K., Titov A. A., Filippov O. A., Smol’yakov A. F., Titova E., epstein L. M., Shubina E. S. Luminescent Ag I Complexes with 2,2′‐Bipyridine Derivatives Featuring [Ag‐(CF 3 ) 2 Pyrazolate] 4 Units // European Journal of Inorganic Chemistry. 2019. Vol. 2019. No. 45. pp. 4855-4861.

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TY - JOUR

DO - 10.1002/ejic.201901050

UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201901050

TI - Luminescent Ag I Complexes with 2,2′‐Bipyridine Derivatives Featuring [Ag‐(CF 3 ) 2 Pyrazolate] 4 Units

T2 - European Journal of Inorganic Chemistry

AU - Emashova, Sofia K

AU - Titov, Aleksei A

AU - Filippov, Oleg A.

AU - Smol’yakov, Alexander F.

AU - Titova, Ekaterina

AU - epstein, Lina M.

AU - Shubina, Elena S.

PY - 2019

DA - 2019/12/02

PB - Wiley

SP - 4855-4861

IS - 45

VL - 2019

SN - 1434-1948

SN - 1099-0682

ER -

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@article{2019_Emashova,

author = {Sofia K Emashova and Aleksei A Titov and Oleg A. Filippov and Alexander F. Smol’yakov and Ekaterina Titova and Lina M. epstein and Elena S. Shubina},

title = {Luminescent Ag I Complexes with 2,2′‐Bipyridine Derivatives Featuring [Ag‐(CF 3 ) 2 Pyrazolate] 4 Units},

journal = {European Journal of Inorganic Chemistry},

year = {2019},

volume = {2019},

publisher = {Wiley},

month = {dec},

url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201901050},

number = {45},

pages = {4855--4861},

doi = {10.1002/ejic.201901050}

}

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Emashova, Sofia K., et al. “Luminescent Ag I Complexes with 2,2′‐Bipyridine Derivatives Featuring [Ag‐(CF 3 ) 2 Pyrazolate] 4 Units.” European Journal of Inorganic Chemistry, vol. 2019, no. 45, Dec. 2019, pp. 4855-4861. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201901050.