A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Laboratory of Metal Hydrides

Organometallic chemistry Chemistry of coordination compounds Physical Chemistry

Head of Laboratory

Shubina, Elena S

DSc in Chemistry, Professor

Publications

255

Citations

5 439

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Lab website

Novel types of hydrogen bonding involving organometallic compounds and transition metal hydridesIntermolecular interactions and reactivity of main group hydrides including polyhedral boron compounds

Supramolecular design based on macrocyclic pyrazolates of copper(I) or silver(I) and organometallic compoundsMetal-oxo clusters with organoelement and organic ligands

IR spectroscopy
DFT calculations
Improved organic synthesis
Various types of inorganic syntheses: hydro (solvo) thermal, sol-gel, solid-phase
NMR spectroscopy
Absorption spectroscopy
UV spectroscopy
Photoluminescence

Elena Shubina

Head of Laboratory

Oleg Filippov 🥼

Leading researcher

Research directions

Metal-oxo clusters with organoelement and organic ligands

Cage-like compounds with metal oxo core, bound to heterochained ligands Study of cage’ self-assembling and rearrangements, especially in the presence of additional organic ligands (“double ligation principle”) Study of supramolecular assembling of cage compounds Study of complexes’ structure in solid state (X-ray, XPD, EXAFS) and solution (IR/UV) Study of cage activity as precatalysts in wide range of processes Study of cage’ molecular magnetism

Supramolecular design based on macrocyclic pyrazolates of copper(I) or silver(I) and organometallic compounds

Intermolecular interactions and reactivity of main group hydrides including polyhedral boron compounds

Novel types of hydrogen bonding involving organometallic compounds and transition metal hydrides

Mechanistic studies of stoichiometric and catalytic reactions involving migration of hydrogen ions. The studies are performed using combination of low temperature molecular spectroscopy measurements and quantum chemical calculations.