volume 2007 issue 30 pages 5082-5094

Synthesis, Structure, and Theoretical Study of Lower Trifluoromethyl Derivatives of [60]Fullerene

Evgenii I Dorozhkin 1
A. Goryunkov 1
Ilya Ioffe 1
Nadezhda B Tamm 1
Daria V Ignateva 1
Lev N. Sidorov 1
Publication typeJournal Article
Publication date2007-10-01
scimago Q2
wos Q2
SJR0.558
CiteScore4.3
Impact factor2.7
ISSN1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
A number of C60(CF3)n compounds with n = 2–10 have been synthesized by the reaction of C60 with silver trifluoroacetate and successfully isolated by means of HPLC. This resulted in the first crystal structure determination of six lower trifluoromethyl derivatives with n = 2 (single isomer), 4 (two isomers), and 6 (three isomers). A kinetic model of sequential trifluoromethylation based on the Bell–Evans–Polanyi principle has been used to explain the experimentally observed isomeric distribution in the mixtures of C60(CF3)n compounds up ton = 6. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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Dorozhkin E. I. et al. Synthesis, Structure, and Theoretical Study of Lower Trifluoromethyl Derivatives of [60]Fullerene // European Journal of Organic Chemistry. 2007. Vol. 2007. No. 30. pp. 5082-5094.
GOST all authors (up to 50) Copy
Dorozhkin E. I., Goryunkov A., Ioffe I., Avdoshenko S., Markov V., Tamm N. B., Ignateva D. V., Sidorov L. N., Troyanov S. Synthesis, Structure, and Theoretical Study of Lower Trifluoromethyl Derivatives of [60]Fullerene // European Journal of Organic Chemistry. 2007. Vol. 2007. No. 30. pp. 5082-5094.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/ejoc.200700487
UR - https://doi.org/10.1002/ejoc.200700487
TI - Synthesis, Structure, and Theoretical Study of Lower Trifluoromethyl Derivatives of [60]Fullerene
T2 - European Journal of Organic Chemistry
AU - Dorozhkin, Evgenii I
AU - Goryunkov, A.
AU - Ioffe, Ilya
AU - Avdoshenko, Stanislav
AU - Markov, Vitaliy
AU - Tamm, Nadezhda B
AU - Ignateva, Daria V
AU - Sidorov, Lev N.
AU - Troyanov, Sergey
PY - 2007
DA - 2007/10/01
PB - Wiley
SP - 5082-5094
IS - 30
VL - 2007
SN - 1434-193X
SN - 1099-0690
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Dorozhkin,
author = {Evgenii I Dorozhkin and A. Goryunkov and Ilya Ioffe and Stanislav Avdoshenko and Vitaliy Markov and Nadezhda B Tamm and Daria V Ignateva and Lev N. Sidorov and Sergey Troyanov},
title = {Synthesis, Structure, and Theoretical Study of Lower Trifluoromethyl Derivatives of [60]Fullerene},
journal = {European Journal of Organic Chemistry},
year = {2007},
volume = {2007},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/ejoc.200700487},
number = {30},
pages = {5082--5094},
doi = {10.1002/ejoc.200700487}
}
MLA
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MLA Copy
Dorozhkin, Evgenii I., et al. “Synthesis, Structure, and Theoretical Study of Lower Trifluoromethyl Derivatives of [60]Fullerene.” European Journal of Organic Chemistry, vol. 2007, no. 30, Oct. 2007, pp. 5082-5094. https://doi.org/10.1002/ejoc.200700487.