Synthesis and copper(I)-driven disaggregation of a zinc-complexed phthalocyanine bearing four lateral coordinating rings
Тип публикации: Journal Article
Дата публикации: 2012-10-29
SCImago Q2
WOS Q2
БС2
SJR: 0.497
CiteScore: 4.2
Impact factor: 2.8
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A new zinc phthalocyaninate, bearing four flexible phenanthroline‐containing 30‐membered rings was synthesized by template condensation of a macrocyclic phthalonitrile. The resulting phthalocyanine was an insoluble aggregate. However, in the presence of CuI ions, the formation of a soluble complex was observed. UV/Vis and DOSY NMR spectroscopic studies showed a monomolecular state for this species in solution. 1H‐1H ROESY demonstrated that the macrocyclic substituents adopt a folded conformation, giving the complex a globular shape. The folding originates from stacking interactions between the phthalocyanine core and peripheral copper(I)–phenanthroline complexes.
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Martynov A. G. et al. Synthesis and copper(I)-driven disaggregation of a zinc-complexed phthalocyanine bearing four lateral coordinating rings // European Journal of Organic Chemistry. 2012. Vol. 2012. No. 35. pp. 6888-6894.
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Martynov A. G., Gorbunova Y. G., Nefedov S. E., Tsivadze A. Yu., Gryko D. T. Synthesis and copper(I)-driven disaggregation of a zinc-complexed phthalocyanine bearing four lateral coordinating rings // European Journal of Organic Chemistry. 2012. Vol. 2012. No. 35. pp. 6888-6894.
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TY - JOUR
DO - 10.1002/ejoc.201200944
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.201200944
TI - Synthesis and copper(I)-driven disaggregation of a zinc-complexed phthalocyanine bearing four lateral coordinating rings
T2 - European Journal of Organic Chemistry
AU - Martynov, Alexander G.
AU - Gorbunova, Yulia G.
AU - Nefedov, Sergey E.
AU - Tsivadze, Aslan Yu
AU - Gryko, Daniel T
PY - 2012
DA - 2012/10/29
PB - Wiley
SP - 6888-6894
IS - 35
VL - 2012
SN - 1434-193X
SN - 1099-0690
ER -
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@article{2012_Martynov,
author = {Alexander G. Martynov and Yulia G. Gorbunova and Sergey E. Nefedov and Aslan Yu Tsivadze and Daniel T Gryko},
title = {Synthesis and copper(I)-driven disaggregation of a zinc-complexed phthalocyanine bearing four lateral coordinating rings},
journal = {European Journal of Organic Chemistry},
year = {2012},
volume = {2012},
publisher = {Wiley},
month = {oct},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.201200944},
number = {35},
pages = {6888--6894},
doi = {10.1002/ejoc.201200944}
}
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Martynov, Alexander G., et al. “Synthesis and copper(I)-driven disaggregation of a zinc-complexed phthalocyanine bearing four lateral coordinating rings.” European Journal of Organic Chemistry, vol. 2012, no. 35, Oct. 2012, pp. 6888-6894. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.201200944.
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