Wiley
European Journal of Organic Chemistry
,  том 2018 ,  издание 7 ,  страницы 879-884

Direct Oxidation of Cyclopropanated Cyclooctanes as a Synthetic Approach to Polycyclic Cyclopropyl Ketones

Тип публикации: Journal Article
Дата публикации: 2018-02-15
Wiley
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SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A series of polycyclic hydrocarbons containing cyclopropane moieties 1,2-annelated or spiro-condensed with cyclooctane ring were investigated under oxidative conditions. Four oxidizing systems (O3 on SiO2, dioxirane derived from trifluoroacetone, CrO3 and RuO4, generated in situ), were employed to evaluate and compare their reactivity and usefulness. RuO4 was found to be the best one, considering its oxidative power together with a simple preparative procedure. The conditions for specific oxidation of polycyclic hydrocarbons were found. Novel cyclooctane derivatives containing cyclopropyl carbonyl moieties were obtained.
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Sedenkova K. N. et al. Direct Oxidation of Cyclopropanated Cyclooctanes as a Synthetic Approach to Polycyclic Cyclopropyl Ketones // European Journal of Organic Chemistry. 2018. Vol. 2018. No. 7. pp. 879-884.
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Sedenkova K. N., Andriasov K. S., Stepanova S. A., Gloriozov I. P., Grishin Y., Kuznetsova T. S., Averina E. B. Direct Oxidation of Cyclopropanated Cyclooctanes as a Synthetic Approach to Polycyclic Cyclopropyl Ketones // European Journal of Organic Chemistry. 2018. Vol. 2018. No. 7. pp. 879-884.
RIS |
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TY - JOUR
DO - 10.1002/ejoc.201701671
UR - https://doi.org/10.1002/ejoc.201701671
TI - Direct Oxidation of Cyclopropanated Cyclooctanes as a Synthetic Approach to Polycyclic Cyclopropyl Ketones
T2 - European Journal of Organic Chemistry
AU - Sedenkova, Kseniya N
AU - Andriasov, Kristian S.
AU - Stepanova, Svetlana A
AU - Gloriozov, Igor P.
AU - Grishin, Yuri
AU - Kuznetsova, Tamara S.
AU - Averina, E. B.
PY - 2018
DA - 2018/02/15
PB - Wiley
SP - 879-884
IS - 7
VL - 2018
SN - 1434-193X
SN - 1099-0690
ER -
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@article{2018_Sedenkova,
author = {Kseniya N Sedenkova and Kristian S. Andriasov and Svetlana A Stepanova and Igor P. Gloriozov and Yuri Grishin and Tamara S. Kuznetsova and E. B. Averina},
title = {Direct Oxidation of Cyclopropanated Cyclooctanes as a Synthetic Approach to Polycyclic Cyclopropyl Ketones},
journal = {European Journal of Organic Chemistry},
year = {2018},
volume = {2018},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/ejoc.201701671},
number = {7},
pages = {879--884},
doi = {10.1002/ejoc.201701671}
}
MLA
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Sedenkova, Kseniya N., et al. “Direct Oxidation of Cyclopropanated Cyclooctanes as a Synthetic Approach to Polycyclic Cyclopropyl Ketones.” European Journal of Organic Chemistry, vol. 2018, no. 7, Feb. 2018, pp. 879-884. https://doi.org/10.1002/ejoc.201701671.