Rhodium‐Catalyzed C−H Activation/Annulation of Aryl Hydroxamates with Benzothiadiazol‐Containing Acetylenes: Access to Isoquinoline‐Bridged Donor‐Acceptor Luminophores
Pavel S Gribanov
1
,
Daria V Vorobyeva
1
,
Sergey D Tokarev
1
,
Dmitry A Petropavlovskikh
1
,
Dmitry A Loginov
1
,
Sergey E. Nefedov
2
,
Publication type: Journal Article
Publication date: 2022-04-03
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
An efficient strategy for the preparation of a novel series of benzothiadiazole‐containing isoquinoline‐bridged D‐A compounds based on Cp*Rh(III)‐catalyzed redox‐neutral annulation ofN‐(pivaloyloxy)‐benzamides with 4‐ethynyl‐7‐(p‐methoxyphenyl)‐2,1,3‐benzothiadiazole as a key step followed by the installation of donor units, such as diphenylamine, carbazole, and dihydrodibenzoazepine, by aromatization and Suzuki coupling reactions, has been developed. An initial photophysical, electrochemical and DFT investigations of the selected products have been performed.
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8
Total citations:
8
Citations from 2024:
4
(50%)
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Gribanov P. S. et al. Rhodium‐Catalyzed C−H Activation/Annulation of Aryl Hydroxamates with Benzothiadiazol‐Containing Acetylenes: Access to Isoquinoline‐Bridged Donor‐Acceptor Luminophores // European Journal of Organic Chemistry. 2022. Vol. 2022. No. 13.
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Gribanov P. S., Vorobyeva D. V., Tokarev S. D., Petropavlovskikh D. A., Loginov D. A., Nefedov S. E., Dolgushin F. M., Osipov S. N. Rhodium‐Catalyzed C−H Activation/Annulation of Aryl Hydroxamates with Benzothiadiazol‐Containing Acetylenes: Access to Isoquinoline‐Bridged Donor‐Acceptor Luminophores // European Journal of Organic Chemistry. 2022. Vol. 2022. No. 13.
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TY - JOUR
DO - 10.1002/ejoc.202101572
UR - https://doi.org/10.1002/ejoc.202101572
TI - Rhodium‐Catalyzed C−H Activation/Annulation of Aryl Hydroxamates with Benzothiadiazol‐Containing Acetylenes: Access to Isoquinoline‐Bridged Donor‐Acceptor Luminophores
T2 - European Journal of Organic Chemistry
AU - Gribanov, Pavel S
AU - Vorobyeva, Daria V
AU - Tokarev, Sergey D
AU - Petropavlovskikh, Dmitry A
AU - Loginov, Dmitry A
AU - Nefedov, Sergey E.
AU - Dolgushin, Fedor M.
AU - Osipov, Sergey N.
PY - 2022
DA - 2022/04/03
PB - Wiley
IS - 13
VL - 2022
SN - 1434-193X
SN - 1099-0690
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Gribanov,
author = {Pavel S Gribanov and Daria V Vorobyeva and Sergey D Tokarev and Dmitry A Petropavlovskikh and Dmitry A Loginov and Sergey E. Nefedov and Fedor M. Dolgushin and Sergey N. Osipov},
title = {Rhodium‐Catalyzed C−H Activation/Annulation of Aryl Hydroxamates with Benzothiadiazol‐Containing Acetylenes: Access to Isoquinoline‐Bridged Donor‐Acceptor Luminophores},
journal = {European Journal of Organic Chemistry},
year = {2022},
volume = {2022},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/ejoc.202101572},
number = {13},
doi = {10.1002/ejoc.202101572}
}