Total Synthesis of (−)‐Cannabidiol‐C 4
Paola Marzullo
1
,
Alice Maiocchi
1
,
Giuseppe Paladino
2
,
Umberto Ciriello
2
,
Leonardo Lo Presti
1
,
Daniele Passarella
1
2
LINNEA SA 6595 Riazzino (TI) Switzerland
|
Publication type: Journal Article
Publication date: 2022-06-08
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
The total synthesis of CBD-C4 (cannabidibutol) is reported. The enantioselective synthesis is based on a) the use 3,5-dimetoxybenzaldehyde as starting material, b) Corey-Bakshi-Shibata reduction, c) Claisen-Ireland rearrangement, d) ring-closing metathesis, and e) not-trivial demethylation induced by sodium ethanethiolate.
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Metrics
12
Total citations:
12
Citations from 2024:
8
(66.67%)
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GOST
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Marzullo P. et al. Total Synthesis of (−)‐Cannabidiol‐C 4 // European Journal of Organic Chemistry. 2022. Vol. 2022. No. 22.
GOST all authors (up to 50)
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Marzullo P., Maiocchi A., Paladino G., Ciriello U., Lo Presti L., Passarella D. Total Synthesis of (−)‐Cannabidiol‐C 4 // European Journal of Organic Chemistry. 2022. Vol. 2022. No. 22.
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RIS
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TY - JOUR
DO - 10.1002/ejoc.202200392
UR - https://doi.org/10.1002/ejoc.202200392
TI - Total Synthesis of (−)‐Cannabidiol‐C 4
T2 - European Journal of Organic Chemistry
AU - Marzullo, Paola
AU - Maiocchi, Alice
AU - Paladino, Giuseppe
AU - Ciriello, Umberto
AU - Lo Presti, Leonardo
AU - Passarella, Daniele
PY - 2022
DA - 2022/06/08
PB - Wiley
IS - 22
VL - 2022
SN - 1434-193X
SN - 1099-0690
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Marzullo,
author = {Paola Marzullo and Alice Maiocchi and Giuseppe Paladino and Umberto Ciriello and Leonardo Lo Presti and Daniele Passarella},
title = {Total Synthesis of (−)‐Cannabidiol‐C 4},
journal = {European Journal of Organic Chemistry},
year = {2022},
volume = {2022},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/ejoc.202200392},
number = {22},
doi = {10.1002/ejoc.202200392}
}