Open Access
Selective side-chain oxidation of peralkylated pyrromethene?BF2 complexes
1
Department of Chemistry University of New Orleans , New Orleans, La, 70148
Publication type: Journal Article
Publication date: 1994-06-01
scimago Q4
wos Q3
SJR: 0.146
CiteScore: 2.3
Impact factor: 1.4
ISSN: 10427163, 10981071
General Chemistry
Abstract
Treatment with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) oxidized 2,6-diethyl-1,3,5,7,8-pentamethylpyrromethene–BF2 complex 1, 13,14-trimethyl-2, 3, 4, 5,9,10,11,12-octahydroindomethene–BF2 complex 5, and 1,3,5,7,8-pentamethyl-1,2,3,5,6,7-hexahydropyromethene–BF2 complex 8 to the weakly fluorescent 3-formyl, 5-oxo, and 8-formyl derivatives 4, 6, and 9, respectively. The dye 1 was oxidized by lead tetraacetate to 1,7,8-trimethyl-2,6-diethyl-3,5-diacetoxymethylpyrromethene–BF2 complex 12 [λf (ethanol) 538 nm, Φ 0.62, λlas (ethanol) 555–570 nm]. Catalytic reduction (Pd/C) converted the aldehyde 4 to 2,6-diethyl-3-hydroxymethyl-1,5,7,8-tetramethylpyrromethene–BF2 complex 10 [λf (ethanol) 537 nm, Φ 0.70, λlas (ethanol) 547–575 nm].
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Total citations:
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Citations from 2024:
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(3.5%)
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GOST
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Sathyamoorthi G. et al. Selective side-chain oxidation of peralkylated pyrromethene?BF2 complexes // Heteroatom Chemistry. 1994. Vol. 5. No. 3. pp. 245-249.
GOST all authors (up to 50)
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Sathyamoorthi G., Wolford L. T., Haag A. M., Boyer J. H. Selective side-chain oxidation of peralkylated pyrromethene?BF2 complexes // Heteroatom Chemistry. 1994. Vol. 5. No. 3. pp. 245-249.
Cite this
RIS
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TY - JOUR
DO - 10.1002/hc.520050309
UR - https://doi.org/10.1002/hc.520050309
TI - Selective side-chain oxidation of peralkylated pyrromethene?BF2 complexes
T2 - Heteroatom Chemistry
AU - Sathyamoorthi, Govindarao
AU - Wolford, Lionel T.
AU - Haag, Anthony M.
AU - Boyer, Joseph H.
PY - 1994
DA - 1994/06/01
PB - Wiley
SP - 245-249
IS - 3
VL - 5
SN - 1042-7163
SN - 1098-1071
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1994_Sathyamoorthi,
author = {Govindarao Sathyamoorthi and Lionel T. Wolford and Anthony M. Haag and Joseph H. Boyer},
title = {Selective side-chain oxidation of peralkylated pyrromethene?BF2 complexes},
journal = {Heteroatom Chemistry},
year = {1994},
volume = {5},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/hc.520050309},
number = {3},
pages = {245--249},
doi = {10.1002/hc.520050309}
}
Cite this
MLA
Copy
Sathyamoorthi, Govindarao, et al. “Selective side-chain oxidation of peralkylated pyrromethene?BF2 complexes.” Heteroatom Chemistry, vol. 5, no. 3, Jun. 1994, pp. 245-249. https://doi.org/10.1002/hc.520050309.